PMID- 10739030 OWN - NLM STAT- MEDLINE DCOM- 20000511 LR - 20220330 IS - 0045-6535 (Print) IS - 0045-6535 (Linking) VI - 40 IP - 9-11 DP - 2000 May-Jun TI - Degradation half-life times of PCDDs, PCDFs and PCBs for environmental fate modeling. PG - 943-9 AB - Literature search of the knowledge on the degradation of persistent organic pollutants (POPs) in environmental compartments air, water, soil and sediment was done in purpose to find properties of POPs of interest for modeling. One degradation process, hydrolysis (chemical degradation), was omitted as negligibly slow for POPs studied. The other two, photolysis and biodegradation processes, were considered separately in purpose to develop estimation procedures. The estimates can be given as pseudo first-order rate constants kP for photolysis and kB for biodegradation. For each compartment, an overall degradation rate is k(tot) = kP + kB and lifetime t(1/2) = ln 2/k(tot). The latter values, lifetimes in each compartment, will be used as input parameters to the Baltic Sea model. FAU - Sinkkonen, S AU - Sinkkonen S AD - Department of Chemistry, University of Jyvaskyla, Finland. FAU - Paasivirta, J AU - Paasivirta J LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't PL - England TA - Chemosphere JT - Chemosphere JID - 0320657 RN - 0 (Benzofurans) RN - 0 (Environmental Pollutants) RN - 0 (Polychlorinated Dibenzodioxins) RN - 0 (Polymers) RN - 0 (polychlorodibenzofuran) RN - DFC2HB4I0K (Polychlorinated Biphenyls) SB - IM MH - Benzofurans/*chemistry MH - Biodegradation, Environmental MH - *Environmental Pollutants MH - *Half-Life MH - Kinetics MH - Photolysis MH - Polychlorinated Biphenyls/*chemistry MH - Polychlorinated Dibenzodioxins/*analogs & derivatives/chemistry MH - Polymers/*chemistry EDAT- 2000/03/30 09:00 MHDA- 2000/05/16 09:00 CRDT- 2000/03/30 09:00 PHST- 2000/03/30 09:00 [pubmed] PHST- 2000/05/16 09:00 [medline] PHST- 2000/03/30 09:00 [entrez] AID - S0045-6535(99)00337-9 [pii] AID - 10.1016/s0045-6535(99)00337-9 [doi] PST - ppublish SO - Chemosphere. 2000 May-Jun;40(9-11):943-9. doi: 10.1016/s0045-6535(99)00337-9.