PMID- 11883650
OWN - NLM
STAT- MEDLINE
DCOM- 20020827
LR  - 20190720
IS  - 0021-9673 (Print)
IS  - 0021-9673 (Linking)
VI  - 947
IP  - 2
DP  - 2002 Feb 22
TI  - Determination of chlorophenols by solid-phase microextraction and liquid 
      chromatography with electrochemical detection.
PG  - 155-65
AB  - A solid-phase microextraction method has been developed for the determination of 
      19 chlorophenols (CPs) in environmental samples. The analytical procedure 
      involves direct sampling of CPs from water using solid-phase microextraction 
      (SPME) and determination by liquid chromatography with electrochemical detection 
      (LC-ED). Three kinds of fibre [50 microm carbowax-templated resin (CW-TPR), 60 
      microm polydimethylsiloxane-divinylbenzene (PDMS-DVB) and 85 microm polyacrylate 
      (PA)] were evaluated for the analysis of CPs. Of these fibres, CW-TPR is the most 
      suitable for the determination of CPs in water. Optimal conditions for both 
      desorption and absorption SPME processes, such as composition of the desorption 
      solvent (water-acetonitrile-methanol, 20:30:50) and desorption time (5 min), 
      extraction time (50 min) and temperature (40 degrees C) as well as pH (3.5) and 
      ionic strength (6 g NaCl) were established. The precision of the SPME-LC-ED 
      method gave relative standard deviations (RSDs) of between 4 and 11%. The method 
      was linear over three to four orders of magnitude and the detection limits, from 
      3 to 8 ng l(-1), were lower than the European Community legislation limits for 
      drinking water. The method was applied to the analysis of CPs in drinking water 
      and wood samples.
FAU - Sarrion, M N
AU  - Sarrion MN
AD  - Departament de Quimica Analitica, Facultat de Quimica, Universitat de Barcelona, 
      Spain.
FAU - Santos, F J
AU  - Santos FJ
FAU - Galceran, M T
AU  - Galceran MT
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
PL  - Netherlands
TA  - J Chromatogr A
JT  - Journal of chromatography. A
JID - 9318488
RN  - 0 (Chlorophenols)
SB  - IM
MH  - Chlorophenols/*analysis
MH  - Chromatography, Liquid/*methods
MH  - Electrochemistry
MH  - Hydrogen-Ion Concentration
MH  - Osmolar Concentration
MH  - Reproducibility of Results
EDAT- 2002/03/09 10:00
MHDA- 2002/08/28 10:01
CRDT- 2002/03/09 10:00
PHST- 2002/03/09 10:00 [pubmed]
PHST- 2002/08/28 10:01 [medline]
PHST- 2002/03/09 10:00 [entrez]
AID - S0021-9673(01)01609-0 [pii]
AID - 10.1016/s0021-9673(01)01609-0 [doi]
PST - ppublish
SO  - J Chromatogr A. 2002 Feb 22;947(2):155-65. doi: 10.1016/s0021-9673(01)01609-0.