PMID- 11993884 OWN - NLM STAT- MEDLINE DCOM- 20021104 LR - 20190714 IS - 0013-936X (Print) IS - 0013-936X (Linking) VI - 36 IP - 8 DP - 2002 Apr 15 TI - Effect of environmental conditions on the permeability of high density polyethylene film to fumigant vapors. PG - 1833-8 AB - Soil fumigation in greenhouses or agricultural fields often includes tarping the soil surface with polyethylene (PE) films to contain the fumigant in the soil and reduce emissions to the atmosphere. Previous research has demonstrated that PE films are permeable to methyl bromide and other fumigant compounds. In these experiments, the effect of temperature, fumigant mixtures, condensed water, and field aging on the permeability of high-density polyethylene (HDPE) was determined. Mass transfer coefficients (h, a measure of permeability) of the fumigants methyl bromide, 1,3-dichloropropene, propargyl bromide, and chloropicrin across HDPE films were determined. In these studies, temperature and HDPE film type had the largest impact on the h of fumigant compounds across HDPE films. Other factors investigated, including fumigant mixtures, condensed water on the film, and field aging of UV-stabilized film, did not have a significant impact on h. The results of these experiments suggest that the permeability of an intact piece of an agricultural film will increase with increasing temperature but is relatively constant despite changes in other environmental conditions. FAU - Papiernik, Sharon K AU - Papiernik SK AD - USDA-ARS, George E. Brown, Jr. Salinity Laboratory, Riverside, California 92507-4617, USA. spapiernik@ussl.ars.usdo.gov FAU - Yates, Scott R AU - Yates SR LA - eng PT - Journal Article PL - United States TA - Environ Sci Technol JT - Environmental science & technology JID - 0213155 RN - 0 (Pesticides) RN - 059QF0KO0R (Water) RN - 9002-88-4 (Polyethylene) SB - IM MH - *Fumigation MH - Permeability MH - Pesticides/*chemistry MH - Polyethylene/*chemistry MH - Temperature MH - Time Factors MH - Volatilization MH - Water EDAT- 2002/05/08 10:00 MHDA- 2002/11/26 04:00 CRDT- 2002/05/08 10:00 PHST- 2002/05/08 10:00 [pubmed] PHST- 2002/11/26 04:00 [medline] PHST- 2002/05/08 10:00 [entrez] AID - 10.1021/es011252i [doi] PST - ppublish SO - Environ Sci Technol. 2002 Apr 15;36(8):1833-8. doi: 10.1021/es011252i.