PMID- 12502402
OWN - NLM
STAT- MEDLINE
DCOM- 20030221
LR  - 20171116
IS  - 0021-8561 (Print)
IS  - 0021-8561 (Linking)
VI  - 51
IP  - 1
DP  - 2003 Jan 1
TI  - Organic matter effects on phase partition of 1,3-dichloropropene in soil.
PG  - 165-9
AB  - The fumigant 1,3-dichloropropene (1,3-D), in combination with chloropicrin, is 
      considered a major replacement to methyl bromide (MeBr). This study was conducted 
      to better understand phase partitioning of 1,3-D and the role of organic matter 
      in its adsorption to soil. Partition of 1,3-D between air and water (K(H)), and 
      between soil and water (K(f)), was determined by quantifying the concentration in 
      both phases upon equilibrium. At 20 degrees C, the K(H) values of (Z)- and 
      (E)-1,3-D were 0.052 and 0.033, respectively. In four California and Florida 
      soils, the K(f) values of 1,3-D isomers ranged from 0.39 to 8.55, and the K(oc) 
      values ranged from 18 to 60. The relatively high K(H) and low K(f) imply that 
      1,3-D is highly mobile in most soils after subsurface application. Adsorption of 
      1,3-D in native soils and soils amended with manure compost increased with 
      increasing soil organic matter content. This suggests that organic wastes may be 
      applied to soil to increase 1,3-D adsorption, thus reducing its potential for 
      offsite movement.
FAU - Kim, Jung-Ho
AU  - Kim JH
AD  - Department of Environmental Science, Kyungsan University, Korea.
FAU - Gan, Jianying
AU  - Gan J
FAU - Farmer, Walter J
AU  - Farmer WJ
FAU - Yates, Scott R
AU  - Yates SR
FAU - Papiernik, Sharon K
AU  - Papiernik SK
FAU - Dungan, Robert S
AU  - Dungan RS
LA  - eng
PT  - Journal Article
PT  - Research Support, U.S. Gov't, Non-P.H.S.
PL  - United States
TA  - J Agric Food Chem
JT  - Journal of agricultural and food chemistry
JID - 0374755
RN  - 0 (Allyl Compounds)
RN  - 0 (Hydrocarbons, Chlorinated)
RN  - 0 (Insecticides)
RN  - 0 (Soil)
RN  - 059QF0KO0R (Water)
RN  - 9H780918D0 (1,3-dichloro-1-propene)
SB  - IM
MH  - Adsorption
MH  - Air/analysis
MH  - Allyl Compounds/*chemistry
MH  - Chemical Phenomena
MH  - Chemistry, Physical
MH  - Hydrocarbons, Chlorinated
MH  - Insecticides/*chemistry
MH  - Soil/*analysis
MH  - Water/analysis/chemistry
EDAT- 2002/12/28 04:00
MHDA- 2003/02/22 04:00
CRDT- 2002/12/28 04:00
PHST- 2002/12/28 04:00 [pubmed]
PHST- 2003/02/22 04:00 [medline]
PHST- 2002/12/28 04:00 [entrez]
AID - 10.1021/jf025798f [doi]
PST - ppublish
SO  - J Agric Food Chem. 2003 Jan 1;51(1):165-9. doi: 10.1021/jf025798f.