PMID- 12727243
OWN - NLM
STAT- MEDLINE
DCOM- 20030916
LR  - 20121115
IS  - 0043-1354 (Print)
IS  - 0043-1354 (Linking)
VI  - 37
IP  - 10
DP  - 2003 May
TI  - Treatment of trichlorophenol by catalytic oxidation process.
PG  - 2339-46
AB  - The oxidation of 2,4,6-trichlorophenol (TCP) by ferrous-catalyzed hydrogen 
      peroxide was quantified and modeled in the study. TCP was effectively degraded by 
      hydroxyl radicals that were generated by Fe(II)/H(2)O(2) in the oxidation 
      process. The oxidation capacity (OC) of the process depends on the concentrations 
      of oxidant (hydrogen peroxide) and oxidative catalyst (ferrous ion). Up to 99.6% 
      of TCP removal can be achieved in the process, provided the doses of Fe(II) and 
      H(2)O(2) are selected correctly. The OC of the process was successfully predicted 
      through a kinetic approach in a two-stage model with some simple and measurable 
      parameters, which makes the model useful for predicting, controlling and 
      optimizing the catalyzed oxidation process in the degradation of TCP.
FAU - Chu, W
AU  - Chu W
AD  - Department of Civil and Structural Engineering, Research Centre for Urban 
      Environmental Technology and Management, Hong Kong Polytechnic University, Hung 
      Hom, Kowloon, Hong Kong. cewchu@polyu.edu.hk
FAU - Law, C K
AU  - Law CK
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
PL  - England
TA  - Water Res
JT  - Water research
JID - 0105072
RN  - 0 (Chlorophenols)
RN  - 0 (Mutagens)
RN  - 0 (Oxidants)
RN  - 3352-57-6 (Hydroxyl Radical)
RN  - MHS8C5BAUZ (2,4,6-trichlorophenol)
SB  - IM
MH  - Catalysis
MH  - Chlorophenols/*chemistry
MH  - Forecasting
MH  - Hydroxyl Radical/chemistry
MH  - Kinetics
MH  - *Models, Theoretical
MH  - Mutagens/*chemistry
MH  - Oxidants/chemistry
MH  - Oxidation-Reduction
MH  - Water Purification/*methods
EDAT- 2003/05/03 05:00
MHDA- 2003/09/17 05:00
CRDT- 2003/05/03 05:00
PHST- 2003/05/03 05:00 [pubmed]
PHST- 2003/09/17 05:00 [medline]
PHST- 2003/05/03 05:00 [entrez]
AID - S0043-1354(03)00010-1 [pii]
AID - 10.1016/S0043-1354(03)00010-1 [doi]
PST - ppublish
SO  - Water Res. 2003 May;37(10):2339-46. doi: 10.1016/S0043-1354(03)00010-1.