PMID- 12767168
OWN - NLM
STAT- MEDLINE
DCOM- 20040105
LR  - 20131121
IS  - 0020-1669 (Print)
IS  - 0020-1669 (Linking)
VI  - 42
IP  - 11
DP  - 2003 Jun 2
TI  - Water-soluble polymer-bound biomimetic analogues of cytochrome C oxidase catalyze 
      4e- reduction of O2 to water.
PG  - 3384-6
AB  - Activity toward catalytic O(2) reduction by polyacrylic acid (PAA) and 
      polyvinylpyridine (PVP) polymers containing functional analogues of the 
      O(2)-reducing site of cytochrome c oxidase (CcO) has been studied in solution and 
      on the electrode surface. Pronounced effects of the porphyrin microenvironment on 
      the selectivity and turnover frequency of the catalysts were observed.
FAU - Collman, James P
AU  - Collman JP
AD  - Department of Chemistry, Stanford University, Stanford, California 94305, USA. 
      jpc@stanford.edu
FAU - Fudickar, Werner
AU  - Fudickar W
FAU - Shiryaeva, Irina
AU  - Shiryaeva I
LA  - eng
GR  - GM 17880/GM/NIGMS NIH HHS/United States
PT  - Journal Article
PT  - Research Support, U.S. Gov't, Non-P.H.S.
PT  - Research Support, U.S. Gov't, P.H.S.
PL  - United States
TA  - Inorg Chem
JT  - Inorganic chemistry
JID - 0366543
RN  - 0 (Metalloporphyrins)
RN  - 0 (Polymers)
RN  - 059QF0KO0R (Water)
RN  - E1UOL152H7 (Iron)
RN  - EC 1.9.3.1 (Electron Transport Complex IV)
RN  - S88TT14065 (Oxygen)
SB  - IM
MH  - Catalysis
MH  - Electrochemistry
MH  - Electron Transport Complex IV/chemistry/*metabolism
MH  - Iron/chemistry
MH  - Metalloporphyrins/*chemistry
MH  - Molecular Mimicry
MH  - Molecular Structure
MH  - Oxidation-Reduction
MH  - Oxygen/*chemistry/metabolism
MH  - Polymers/chemistry
MH  - Water/*chemistry
EDAT- 2003/05/28 05:00
MHDA- 2004/01/06 05:00
CRDT- 2003/05/28 05:00
PHST- 2003/05/28 05:00 [pubmed]
PHST- 2004/01/06 05:00 [medline]
PHST- 2003/05/28 05:00 [entrez]
AID - 10.1021/ic034140w [doi]
PST - ppublish
SO  - Inorg Chem. 2003 Jun 2;42(11):3384-6. doi: 10.1021/ic034140w.