PMID- 12873009
OWN - NLM
STAT- MEDLINE
DCOM- 20031030
LR  - 20191107
IS  - 0017-467X (Print)
IS  - 0017-467X (Linking)
VI  - 41
IP  - 4
DP  - 2003 Jul-Aug
TI  - Geochemical effects on metals following permanganate oxidation of DNAPLs.
PG  - 458-69
AB  - The application of in situ chemical oxidation for dense, nonaqueous phase liquid 
      (DNAPL) remediation requires delivery of substantial levels of oxidant chemicals 
      into the subsurface to degrade target DNAPLs and to satisfy natural oxidant 
      demand. This practice can raise questions regarding changes in subsurface 
      conditions, yet information regarding potential effects, especially at the field 
      scale, has been lacking. This paper describes an evaluation of the effects on 
      metals associated with in situ chemical oxidation using potassium permanganate at 
      Launch Complex 34 (LC34), Cape Canaveral Air Station, Florida. At LC34, high 
      concentrations of permanganate (1 to 2 wt%) were injected into the subsurface as 
      part of a demonstration of DNAPL remediation technologies. In a companion 
      experimental effort at the Colorado School of Mines, field samples were 
      characterized and laboratory batch and mini-column studies were completed to 
      assess effects of permanganate oxidation on metals in the subsurface one year 
      after completion of the field demonstration. Results indicated there was 
      potential for long-term immobilization of a portion of introduced manganese and 
      no treatment-induced loss in subsurface permeability due to deposition of 
      manganese oxides particles, which are a product of the oxidation reactions. 
      Permanganate treatment did cause elevated manganese, chromium, and nickel 
      concentrations in site ground water within the treated region. Some of these 
      metals effects can be attenuated during downgradient flow through uncontaminated 
      and untreated aquifer sediments.
FAU - Crimi, Michelle L
AU  - Crimi ML
AD  - Colorado School of Mines, Environmental Science and Engineering Division, Golden, 
      CO 80401, USA. mcrimi@mines.edu
FAU - Siegrist, Robert L
AU  - Siegrist RL
LA  - eng
PT  - Journal Article
PL  - United States
TA  - Ground Water
JT  - Ground water
JID - 9882886
RN  - 0 (Manganese Compounds)
RN  - 0 (Metals, Heavy)
RN  - 0 (Oxidants)
RN  - 0 (Oxides)
RN  - 0 (Soil Pollutants)
RN  - 0 (Water Pollutants)
RN  - 14333-13-2 (permanganic acid)
SB  - IM
MH  - Environmental Pollution/prevention & control
MH  - Geologic Sediments
MH  - Manganese Compounds/*chemistry
MH  - Metals, Heavy/*chemistry
MH  - Oxidants/*chemistry
MH  - Oxidation-Reduction
MH  - Oxides/*chemistry
MH  - *Soil Pollutants
MH  - Water Movements
MH  - *Water Pollutants
EDAT- 2003/07/23 05:00
MHDA- 2003/10/31 05:00
CRDT- 2003/07/23 05:00
PHST- 2003/07/23 05:00 [pubmed]
PHST- 2003/10/31 05:00 [medline]
PHST- 2003/07/23 05:00 [entrez]
AID - 10.1111/j.1745-6584.2003.tb02380.x [doi]
PST - ppublish
SO  - Ground Water. 2003 Jul-Aug;41(4):458-69. doi: 10.1111/j.1745-6584.2003.tb02380.x.