PMID- 14613138
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20041013
LR  - 20090804
IS  - 0947-6539 (Print)
IS  - 0947-6539 (Linking)
VI  - 9
IP  - 21
DP  - 2003 Nov 7
TI  - Nanomorphology of polymer frameworks and their role as templates for generating 
      size-controlled metal nanoclusters.
PG  - 5292-6
AB  - The microporous (gel-type) functional resin co-poly-N,N-dimethylacrylamide (DMAA) 
      (88 % mol)/methacrylic acid (MAA) (8 % mol)/N,N'-methylenebisacrylamide (MBAA) (4 
      % mol) (MPIF(H)) is employed as the hosting framework for the production of 
      resin-supported Pd(0) nanoclusters. The obtained composite MPIF(-)Na(+)/Pd(0) is 
      prepared upon reducing, in ethanol, MPIF(-)Pd(2+) (0.5), obtained upon previous 
      homogeneous dispersion of "Pd(2+)" inside the resin particles (XRMA control) 
      through ion-exchange. Metal nanoclusters appear to be size-controlled (2.0+/-0.2 
      nm) and are seen to reasonably fit the predominant resin "nanopores" diameter, 
      determined in ethanol (3.2 nm) by means of inverse steric exclusion 
      chromatography (ISEC).
FAU - Artuso, Frederica
AU  - Artuso F
AD  - Istituto di Scienze e Tecnologie Molecolari, CNR, Sezione di Padova, c/o 
      Dipartimento di Chimica Inorganica Metallorganica Analitica, Via Marzolo 1, 35131 
      Padova, Italy.
FAU - D'Archivio, Angelo A
AU  - D'Archivio AA
FAU - Lora, Silvano
AU  - Lora S
FAU - Jerabek, Karel
AU  - Jerabek K
FAU - Kralik, Milan
AU  - Kralik M
FAU - Corain, Benedetto
AU  - Corain B
LA  - eng
PT  - Journal Article
PL  - Germany
TA  - Chemistry
JT  - Chemistry (Weinheim an der Bergstrasse, Germany)
JID - 9513783
EDAT- 2003/11/13 05:00
MHDA- 2003/11/13 05:01
CRDT- 2003/11/13 05:00
PHST- 2003/11/13 05:00 [pubmed]
PHST- 2003/11/13 05:01 [medline]
PHST- 2003/11/13 05:00 [entrez]
AID - 10.1002/chem.200304965 [doi]
PST - ppublish
SO  - Chemistry. 2003 Nov 7;9(21):5292-6. doi: 10.1002/chem.200304965.