PMID- 14667726 OWN - NLM STAT- MEDLINE DCOM- 20040610 LR - 20190901 IS - 0269-7491 (Print) IS - 0269-7491 (Linking) VI - 128 IP - 1-2 DP - 2004 TI - Investigating the occurrence of persistent organic pollutants (POPs) in the arctic: their atmospheric behaviour and interaction with the seasonal snow pack. PG - 163-75 AB - POPs in the Arctic are the focus of international concern due to their occurrence and accumulation in Arctic food webs. This paper presents an overview of the major pathways into the Arctic and details contemporary studies that have focused on the occurrence and transfer of POPs between the major Arctic compartments, highlighting areas where there is a lack of quantitative information. The behaviour of these chemicals in the Arctic atmosphere is scrutinised with respect to long-term trends and seasonal behaviour. Subtle differences between the PCBs and OC pesticides are demonstrated and related to sources outside of the Arctic as well as environmental processes within the Arctic. Unlike temperate regions, contaminant fate is strongly affected by the presence of snow and ice. A description of the high Arctic snow pack is given and the physical characteristics that determine chemical fate, namely the specific surface area of snow and wind driven ventilation, are discussed. Using a well-characterised fresh snow event observed at Alert (Canadian high Arctic) [Atmos. Environ. 36(2002) 2767] the flux of gamma-HCH out of the snow is predicted following snow ageing. Under conditions of wind (10 m/s) it is estimated that approximately 75% of the chemical may be re-emitted to the atmosphere within 24 h following snowfall, compared with just approximately 5% under conditions of no wind. The implications of this are raised and areas of further research suggested. FAU - Halsall, Crispin J AU - Halsall CJ AD - Environmental Science Department, Lancaster University, Lancaster, LA1 4YQ, UK. c.halsall@lancaster.ac.uk LA - eng PT - Journal Article PL - England TA - Environ Pollut JT - Environmental pollution (Barking, Essex : 1987) JID - 8804476 RN - 0 (Air Pollutants) RN - 0 (Organic Chemicals) RN - 0 (Pesticides) RN - 0 (Water Pollutants, Chemical) RN - DFC2HB4I0K (Polychlorinated Biphenyls) SB - IM MH - Air Pollutants/*analysis MH - Arctic Regions MH - Atmosphere/chemistry MH - Organic Chemicals/*analysis MH - Pesticides/analysis MH - Polychlorinated Biphenyls/analysis MH - *Seasons MH - *Snow MH - Time Factors MH - Water Pollutants, Chemical/analysis MH - Wind EDAT- 2003/12/12 05:00 MHDA- 2004/06/21 10:00 CRDT- 2003/12/12 05:00 PHST- 2003/12/12 05:00 [pubmed] PHST- 2004/06/21 10:00 [medline] PHST- 2003/12/12 05:00 [entrez] AID - S0269749103003403 [pii] AID - 10.1016/j.envpol.2003.08.026 [doi] PST - ppublish SO - Environ Pollut. 2004;128(1-2):163-75. doi: 10.1016/j.envpol.2003.08.026.