PMID- 14677954
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20040308
LR  - 20080117
IS  - 0002-7863 (Print)
IS  - 0002-7863 (Linking)
VI  - 125
IP  - 51
DP  - 2003 Dec 24
TI  - Chiral bisphosphine BINAP-stabilized gold and palladium nanoparticles with small 
      size and their palladium nanoparticle-catalyzed asymmetric reaction.
PG  - 15742-3
AB  - The reduction of tetrachloroaurate or potassium tetrachloropalladate with sodium 
      borohydride in the presence of optically active 
      2,2'-bis(diphenylphosphino)-1,1'-binaphthyl [BINAP] gave the chiral (S)- or 
      (R)-BINAP-stabilized gold or palladium nanoparticles which showed the small core 
      (1.7 nm for BINAP-Au and 2.0 nm for BINAP-Pd) with narrow size distribution and 
      remarkably high stability. Asymmetric hydrosilylation of styrene with 
      trichlorosilane in the presence of chiral BINAP-Pd nanoparticles afforded an 
      optically active 1-phenyl-1-trichlorosilylethane which was converted into an 
      optically active 1-phenylethanol (95% enantiomeric excess) by oxidative cleavage 
      of the carbon-silicon bond.
FAU - Tamura, Masaru
AU  - Tamura M
AD  - Department of Applied Chemistry and Molecular Engineering Institute, Kinki 
      University, Kowakae, Higashi-Osaka 577-8502, Japan.
FAU - Fujihara, Hisashi
AU  - Fujihara H
LA  - eng
PT  - Journal Article
PL  - United States
TA  - J Am Chem Soc
JT  - Journal of the American Chemical Society
JID - 7503056
EDAT- 2003/12/18 05:00
MHDA- 2003/12/18 05:01
CRDT- 2003/12/18 05:00
PHST- 2003/12/18 05:00 [pubmed]
PHST- 2003/12/18 05:01 [medline]
PHST- 2003/12/18 05:00 [entrez]
AID - 10.1021/ja0369055 [doi]
PST - ppublish
SO  - J Am Chem Soc. 2003 Dec 24;125(51):15742-3. doi: 10.1021/ja0369055.