PMID- 15084097
OWN - NLM
STAT- MEDLINE
DCOM- 20040831
LR  - 20190729
IS  - 1060-3271 (Print)
IS  - 1060-3271 (Linking)
VI  - 87
IP  - 1
DP  - 2004 Jan-Feb
TI  - A gas chromatographic determination of residues of eleven insecticides and two 
      metabolites on olive tree leaves.
PG  - 146-50
AB  - A gas chromatographic (GC) method was developed and statistically validated for 
      the simultaneous determination of residues of pyrethroid, endosulfan, and 
      organophosphorus insecticides and some of their metabolites on olive tree leaves. 
      Pesticide residues were extracted by static extraction with 
      acetone-dichloromethane. After evaporation of the extract to dryness and 
      redissolution in acetone, the organophosphorus insecticides were determined by GC 
      with nitrogen-phosphorus detection. Another portion of the extract, after solvent 
      change to acetonitrile, was cleaned up on an Alumina-N cartridge and analyzed for 
      insecticides sensitive to electron-capture detection (ECD), i.e., pyrethroids and 
      endosulfan and its metabolite. Recoveries of the organophosphorus insecticides 
      ranged from 80.7 to 93.3% with relative standard deviations (RSDs) of < or = 
      7.2%; recoveries of the ECD-sensitive insecticides ranged from 71.6 to 89.5% with 
      RSDs of < or = 11.6%. The method was used to analyze 26 samples of olive tree 
      leaves from organic olive groves all over Greece, and the results confirmed the 
      viability of the method for routine analysis. Residues of fenthion and fenthion 
      sulfoxide were found in one and 3 samples, respectively, and their identities 
      were confirmed by GC with mass spectrometry.
FAU - Aplada-Sarlis, Pipina
AU  - Aplada-Sarlis P
AD  - Benaki Phytopathological Institute, Pesticide Residues Laboratory, 7 Ekalis St, 
      145 61, Kifissia, Greece.
FAU - Miliadis, George E
AU  - Miliadis GE
FAU - Liapis, Konstantinos
AU  - Liapis K
FAU - Tsiropoulos, Nicholas G
AU  - Tsiropoulos NG
LA  - eng
PT  - Journal Article
PL  - England
TA  - J AOAC Int
JT  - Journal of AOAC International
JID - 9215446
RN  - 0 (Indicators and Reagents)
RN  - 0 (Insecticides)
RN  - 0 (Pesticide Residues)
RN  - 0 (Solutions)
SB  - IM
MH  - Chromatography, Gas
MH  - Indicators and Reagents
MH  - Insecticides/*analysis
MH  - Mass Spectrometry
MH  - Olea/*chemistry
MH  - Pesticide Residues/*analysis
MH  - Plant Leaves/chemistry
MH  - Reference Standards
MH  - Solutions
EDAT- 2004/04/16 05:00
MHDA- 2004/09/01 05:00
CRDT- 2004/04/16 05:00
PHST- 2004/04/16 05:00 [pubmed]
PHST- 2004/09/01 05:00 [medline]
PHST- 2004/04/16 05:00 [entrez]
PST - ppublish
SO  - J AOAC Int. 2004 Jan-Feb;87(1):146-50.