PMID- 15327153 OWN - NLM STAT- MEDLINE DCOM- 20041006 LR - 20191108 IS - 0167-6369 (Print) IS - 0167-6369 (Linking) VI - 96 IP - 1-3 DP - 2004 Aug-Sep TI - Kinetics of biotransformation of 2,4-dichlorophenol using UASB-reactor. PG - 129-41 AB - Chlorophenol compounds are environmental pollutants that are both anthropogenic and xenobiotics. Some of these chemicals are carcinogens and are both toxic to a number biochemical processes. Biotransformation of 2,4-dichlorophenol (2,4-DCP) was studied in the presence of glucose on an upflow anaerobic sludge blanket reactor (UASB) using mixed culture. A continuously operated UASB reactor was employed using mixed synthetic wastewater. Results obtained from the 1.8 L volume capacity UASB reactor were subjected to kinetic evaluation constants. Results indicate that the degradation of 2,4-DCP in the presence of glucose was strongly influenced by the concentration of the compound. High degradation levels were observed when the concentration of 2,4-DCP was in the range of 50-150 mg L(-1). Concentrations of 2,4-DCP above 160 mg L(-1) were toxic to microbes even in the presence of glucose. The maximum degradation of 2,4-DCP was found to be 70.4% when initial concentration of 2,4-DCP was 124 mg L(-1) and glucose concentration of 500 mg L(-1) at hydraulic retention time of 13.2 hr. The biodegradation followed first order reaction kinetics with a rate constant (K) of 0.67, Vmax of 0.244 kg m(-3) day(-1), Ks of 0.117 kg m(-3) day(-1) and correlation coefficient of 0.766. FAU - Atuanya, E I AU - Atuanya EI AD - Department of Microbiology, University of Benin, Benin City, Nigeria. atuei@uniben.edu.ng FAU - Chakrabarti, T AU - Chakrabarti T LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't PL - Netherlands TA - Environ Monit Assess JT - Environmental monitoring and assessment JID - 8508350 RN - 0 (Anthelmintics) RN - 0 (Chlorophenols) RN - R669TG1950 (2,4-dichlorophenol) SB - IM MH - Anaerobiosis MH - Anthelmintics MH - *Bioreactors MH - Biotransformation MH - Chlorophenols/*pharmacokinetics MH - Kinetics EDAT- 2004/08/26 05:00 MHDA- 2004/10/07 09:00 CRDT- 2004/08/26 05:00 PHST- 2004/08/26 05:00 [pubmed] PHST- 2004/10/07 09:00 [medline] PHST- 2004/08/26 05:00 [entrez] AID - 10.1023/b:emas.0000031720.86980.2e [doi] PST - ppublish SO - Environ Monit Assess. 2004 Aug-Sep;96(1-3):129-41. doi: 10.1023/b:emas.0000031720.86980.2e.