PMID- 15378888
OWN - NLM
STAT- MEDLINE
DCOM- 20050315
LR  - 20191210
IS  - 0021-9673 (Print)
IS  - 0021-9673 (Linking)
VI  - 1045
IP  - 1-2
DP  - 2004 Aug 6
TI  - Determination of tridemorph and other fungicide residues in fruit samples by 
      liquid chromatography-electrospray tandem mass spectrometry.
PG  - 137-43
AB  - A rapid and sensitive liquid chromatography-electrospray ionization-tandem mass 
      spectrometry (LC-ESI-MS-MS) method for the determination of tridemorph and other 
      pre- and post-harvest fungicides (carbendazim, thiabendazole, imazalil, 
      propiconazole and bitertanol) in banana and orange samples has been developed and 
      validated. The sample preparation was a simple extraction step with acetone using 
      a high-speed blender prior to the injection of the five-fold diluted extract into 
      the LC system with no other previous sample pre-treatment. Quantification was 
      carried out using a matrix matched calibration curve which was linear in the 
      range of 1-100 ng ml(-1) for all the compounds. The limit of quantification was 
      0.05 mg kg(-1) for all studied compounds, whereas limits of detection ranged 
      between 0.005 and 0.025 mg kg(-1) (0.01 mg kg(-1) for tridemorph). Recoveries for 
      tridemorph from spiked banana and orange samples at 0.05 and 1 mg kg(-1) were 
      satisfactory, with values between 83 and 99% and relative standard deviations 
      (R.S.D.s) lower than 13% (n = 5). For the other fungicides, recoveries between 75 
      and 95% with R.S.D.s lower than 12% were obtained. The developed method has been 
      applied to the determination of selected fungicides in real samples of bananas 
      and oranges from different origin. Thiabendazole and imazalil have been detected 
      in almost all orange samples analyzed, and in around of 30% of banana samples. 
      Bitertanol residues exceeded the maximum residue level (0.05 mg kg(-1)) in three 
      banana samples while tridemorph was only detected in one sample.
FAU - Zamora, T
AU  - Zamora T
AD  - Experimental Sciences Department, Analytical Chemistry, University Jaume I, AP 
      12071, Castellon, Spain.
FAU - Pozo, O J
AU  - Pozo OJ
FAU - Lopez, F J
AU  - Lopez FJ
FAU - Hernandez, F
AU  - Hernandez F
LA  - eng
PT  - Journal Article
PT  - Validation Study
PL  - Netherlands
TA  - J Chromatogr A
JT  - Journal of chromatography. A
JID - 9318488
RN  - 0 (Fungicides, Industrial)
RN  - 0 (Morpholines)
RN  - 0YZ4Z668EY (tridemorph)
SB  - IM
MH  - Calibration
MH  - Chromatography, High Pressure Liquid/*methods
MH  - Fruit/*chemistry
MH  - Fungicides, Industrial/*analysis
MH  - Morpholines/*analysis
MH  - Reproducibility of Results
MH  - Spectrometry, Mass, Electrospray Ionization/*methods
EDAT- 2004/09/24 05:00
MHDA- 2005/03/16 09:00
CRDT- 2004/09/24 05:00
PHST- 2004/09/24 05:00 [pubmed]
PHST- 2005/03/16 09:00 [medline]
PHST- 2004/09/24 05:00 [entrez]
AID - S0021-9673(04)00966-5 [pii]
AID - 10.1016/j.chroma.2004.06.041 [doi]
PST - ppublish
SO  - J Chromatogr A. 2004 Aug 6;1045(1-2):137-43. doi: 10.1016/j.chroma.2004.06.041.