PMID- 15504474
OWN - NLM
STAT- MEDLINE
DCOM- 20050324
LR  - 20131121
IS  - 0045-6535 (Print)
IS  - 0045-6535 (Linking)
VI  - 57
IP  - 9
DP  - 2004 Dec
TI  - Decomposition of trichloroethylene and 2,4-dichlorophenol by ozonation in several 
      organic solvents.
PG  - 1151-5
AB  - The effects of chemical characteristics of organic solvents on the decomposition 
      rate constants of undissociative trichloroethylene (TCE) and dissociative 
      2,4-dichlorophenol (2,4-DCP) by ozonation were studied. The TCE and 2,4-DCP 
      decomposition by ozonation in organic solvents followed to the first-order 
      reaction kinetics with respect to TCE or 2,4-DCP concentration. The orders of the 
      rate constants among organic solvents for undissociative TCE and dissociative 
      2,4-DCP were different indicating that the ozonation rates for undissociative and 
      dissociative compounds were dependent on the chemical property of organic 
      solvent. The decomposition of undissociative TCE by ozonation was a simple 
      electrophilic reaction, which was dependent on acceptor number (AN) of the 
      solvent. On the other hand, the decomposition of dissociative 2,4-DCP was 
      dependent on by the dissociation of the compounds and would be dependent on donor 
      number (DN) of the solvent. Finally, TCE in acetic acid was transformed to 
      chlorinated intermediates and chloride ion and then these intermediates were 
      continuously oxidized to chlorine gas.
FAU - Tsai, Tsung-Yueh
AU  - Tsai TY
AD  - Department of Chemical Engineering, Graduate School of Engineering, Hiroshima 
      University, 1-4-1 Kagamiyama, 739-8527 Higashi-Hiroshima, Japan.
FAU - Okawa, Kiyokazu
AU  - Okawa K
FAU - Nakano, Yoichi
AU  - Nakano Y
FAU - Nishijima, Wataru
AU  - Nishijima W
FAU - Okada, Mitsumasa
AU  - Okada M
LA  - eng
PT  - Comparative Study
PT  - Journal Article
PL  - England
TA  - Chemosphere
JT  - Chemosphere
JID - 0320657
RN  - 0 (Chlorides)
RN  - 0 (Chlorophenols)
RN  - 0 (Solvents)
RN  - 290YE8AR51 (Trichloroethylene)
RN  - 66H7ZZK23N (Ozone)
RN  - Q40Q9N063P (Acetic Acid)
RN  - R669TG1950 (2,4-dichlorophenol)
SB  - IM
MH  - Acetic Acid
MH  - Chlorides/chemistry
MH  - Chlorophenols/*chemistry
MH  - Kinetics
MH  - Ozone/*chemistry
MH  - Solvents/*chemistry
MH  - Trichloroethylene/*chemistry
EDAT- 2004/10/27 09:00
MHDA- 2005/03/25 09:00
CRDT- 2004/10/27 09:00
PHST- 2003/10/08 00:00 [received]
PHST- 2004/07/27 00:00 [revised]
PHST- 2004/08/26 00:00 [accepted]
PHST- 2004/10/27 09:00 [pubmed]
PHST- 2005/03/25 09:00 [medline]
PHST- 2004/10/27 09:00 [entrez]
AID - S0045-6535(04)00735-0 [pii]
AID - 10.1016/j.chemosphere.2004.08.081 [doi]
PST - ppublish
SO  - Chemosphere. 2004 Dec;57(9):1151-5. doi: 10.1016/j.chemosphere.2004.08.081.