PMID- 15508316
OWN - NLM
STAT- MEDLINE
DCOM- 20050228
LR  - 20180123
IS  - 0021-9673 (Print)
IS  - 0021-9673 (Linking)
VI  - 1050
IP  - 2
DP  - 2004 Oct 1
TI  - In situ matrix evaporation by isothermal distillation of high-purity reagents for 
      the determination of trace impurities by ion chromatography.
PG  - 223-7
AB  - In situ matrix evaporation of high-purity acids based on isothermal distillation 
      was achieved in a high-density polyethylene (HDPE) container on a water bath, to 
      avoid contamination from the laboratory environment. The solubility of water and 
      acid vapours in glycerol due to co-association was utilized to achieve complete 
      evaporation. All major sources which contribute to the process blank were taken 
      care of in a simple and effective way. A 50-fold preconcentration with >99.9% 
      matrix removal was achieved for the analysis of low-boiling acids, HCl, HF, HNO3 
      and H2O2. The non-volatile ions NH4+, Li+, Na+, K+, Mg2+, Ca2+, SO4(2-) and 
      PO4(3-) were determined by ion chromatograph with conductivity detection. The 
      detection limits were 6-130 ng/l with recoveries of 85-110% for all ions studied.
FAU - Dhavile, S M
AU  - Dhavile SM
AD  - National Centre for Compositional Characterisation of Materials (CCCM), Bhabha 
      Atomic Research Centre, Hyderabad 500062, India.
FAU - Thangavel, S
AU  - Thangavel S
FAU - Chandrasekaran, K
AU  - Chandrasekaran K
FAU - Dash, K
AU  - Dash K
FAU - Rao, S V
AU  - Rao SV
FAU - Chaurasia, S C
AU  - Chaurasia SC
LA  - eng
PT  - Journal Article
PL  - Netherlands
TA  - J Chromatogr A
JT  - Journal of chromatography. A
JID - 9318488
RN  - 0 (Indicators and Reagents)
RN  - 0 (Polyethylenes)
SB  - IM
MH  - Chromatography, Ion Exchange
MH  - Indicators and Reagents/*chemistry
MH  - Polyethylenes
MH  - Reproducibility of Results
MH  - Thermodynamics
EDAT- 2004/10/29 09:00
MHDA- 2005/03/01 09:00
CRDT- 2004/10/29 09:00
PHST- 2004/10/29 09:00 [pubmed]
PHST- 2005/03/01 09:00 [medline]
PHST- 2004/10/29 09:00 [entrez]
AID - S0021-9673(04)01403-7 [pii]
PST - ppublish
SO  - J Chromatogr A. 2004 Oct 1;1050(2):223-7.