PMID- 15729824
OWN - NLM
STAT- MEDLINE
DCOM- 20050705
LR  - 20190720
IS  - 0021-9673 (Print)
IS  - 0021-9673 (Linking)
VI  - 1064
IP  - 1
DP  - 2005 Jan 28
TI  - Determination of odorous mixed chloro-bromoanisoles in water by solid-phase 
      micro-extraction and gas chromatography-mass detection.
PG  - 97-106
AB  - A headspace-solid-phase micro-extraction (HS-SPME) and gas chromatography-mass 
      spectrometry (GC-MS) method has been proposed for the simultaneous determination 
      of odorous trihalogenated anisoles in water. Parameters affecting efficiency of 
      HS-SPME procedure, such as the selection of the SPME coating, extraction time, 
      temperature and ionic strength were optimized. The commercially available 
      polydimethylsiloxane (PDMS 100 microm) fiber appears to be the most suitable for 
      the simultaneous determination of these compounds. Run-to-run precision with 
      relative standard deviations (R.S.D.s) between 5 and 15% were obtained for most 
      of the compounds except for 2,5-dicloro-6-bromo-anisole, 
      2,3-dibromo-6-chloroanisole, pentachloro- and pentabromoanisole (>20%). The 
      method was linear over two orders of magnitude, and detection limits were 
      compound dependent and ranged from 0.03 ng/L for 2,4,6-trichloroanisole to 0.25 
      ng/L for 2,3-dibromo-6-chloroanisole. The HS-SPME-GC-MS procedure was tested 
      using real samples and relatively good standard deviations were obtained when 
      using p-iodoanisole as internal standard for quantification. This is the first 
      time that the individual identification of odorous trihalogenated 
      chloro-bromoanisoles has been reported, being HS-SPME-GC-MS a suitable method for 
      simultaneous determination of these compounds in water at concentration levels 
      below their odor limit of detection.
FAU - Diaz, Alfredo
AU  - Diaz A
AD  - AGBAR, Aigues de Barcelona, Passeig de Sant Joan 39, 08009 Barcelona, Spain.
FAU - Ventura, Francesc
AU  - Ventura F
FAU - Galceran, Maria Teresa
AU  - Galceran MT
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
PL  - Netherlands
TA  - J Chromatogr A
JT  - Journal of chromatography. A
JID - 9318488
RN  - 0 (Anisoles)
SB  - IM
MH  - Anisoles/*analysis
MH  - Gas Chromatography-Mass Spectrometry/*methods
MH  - Water Supply/*analysis
EDAT- 2005/02/26 09:00
MHDA- 2005/07/06 09:00
CRDT- 2005/02/26 09:00
PHST- 2005/02/26 09:00 [pubmed]
PHST- 2005/07/06 09:00 [medline]
PHST- 2005/02/26 09:00 [entrez]
AID - S0021-9673(04)02259-9 [pii]
AID - 10.1016/j.chroma.2004.12.027 [doi]
PST - ppublish
SO  - J Chromatogr A. 2005 Jan 28;1064(1):97-106. doi: 10.1016/j.chroma.2004.12.027.