PMID- 15755096 OWN - NLM STAT- MEDLINE DCOM- 20050428 LR - 20200930 IS - 1530-6984 (Print) IS - 1530-6984 (Linking) VI - 5 IP - 3 DP - 2005 Mar TI - Production and characterization of single-crystal FeCo nanowires inside carbon nanotubes. PG - 467-72 AB - We describe the synthesis of novel monocrystalline FeCo nanowires encapsulated inside multiwalled carbon nanotubes (MWNTs). These FeCo nanowires exhibit homogeneous Fe and Co concentrations and do not contain an external oxide layer due to the presence of insulating nanotube layers. The method involves the aerosol thermolysis of toluene-ferrocene-cobaltocene solutions in inert atmospheres. The materials have been carefully characterized using state-of-the-art high-resolution transmission electron microscopy (HRTEM), electron-energy-loss spectroscopy (EELS), scanning electron microscopy (SEM), energy-dispersive X-ray analysis (EDX), electron diffraction, HREELS-STM elemental mapping, X-ray powder diffraction, and SQUID magnetometry. We noted that the formation of FeCo alloys occurs at relatively low pyrolytic temperatures (e.g., 650-750 degrees C). These single-crystal nanowires, which have not been reported hitherto, always exhibit the FeCo (110) plane parallel to the carbon nanotube axis. The FeCo nanomaterials have shown large coercive fields at room temperature (e.g., 900 Oe). We envisage that these aligned ferromagnetic nanowires could be used in the fabrication of high-density magnetic storage devices and magnetic composites. FAU - Elias, A L AU - Elias AL AD - Advanced Materials Department, IPICYT, Camino a la Presa San Jose 2055, Col. Lomas 4 seccion, San Luis Potosi, 78216, Mexico. FAU - Rodriguez-Manzo, J A AU - Rodriguez-Manzo JA FAU - McCartney, M R AU - McCartney MR FAU - Golberg, D AU - Golberg D FAU - Zamudio, A AU - Zamudio A FAU - Baltazar, S E AU - Baltazar SE FAU - Lopez-Urias, F AU - Lopez-Urias F FAU - Munoz-Sandoval, E AU - Munoz-Sandoval E FAU - Gu, L AU - Gu L FAU - Tang, C C AU - Tang CC FAU - Smith, D J AU - Smith DJ FAU - Bando, Y AU - Bando Y FAU - Terrones, H AU - Terrones H FAU - Terrones, M AU - Terrones M LA - eng PT - Evaluation Study PT - Journal Article PT - Research Support, Non-U.S. Gov't PT - Research Support, U.S. Gov't, Non-P.H.S. PL - United States TA - Nano Lett JT - Nano letters JID - 101088070 RN - 0 (Iron Compounds) RN - 0 (Macromolecular Substances) RN - 0 (Nanotubes, Carbon) RN - 3G0H8C9362 (Cobalt) SB - IM MH - Cobalt/analysis/*chemistry MH - Crystallization/*methods MH - Iron Compounds/analysis/*chemistry MH - Macromolecular Substances/analysis/chemistry MH - *Magnetics MH - Materials Testing MH - Nanotechnology/*methods MH - Nanotubes, Carbon/analysis/*chemistry/*ultrastructure MH - Particle Size MH - Temperature EDAT- 2005/03/10 09:00 MHDA- 2005/04/29 09:00 CRDT- 2005/03/10 09:00 PHST- 2005/03/10 09:00 [pubmed] PHST- 2005/04/29 09:00 [medline] PHST- 2005/03/10 09:00 [entrez] AID - 10.1021/nl0479583 [doi] PST - ppublish SO - Nano Lett. 2005 Mar;5(3):467-72. doi: 10.1021/nl0479583.