PMID- 15819195 OWN - NLM STAT- MEDLINE DCOM- 20050725 LR - 20190714 IS - 0013-936X (Print) IS - 0013-936X (Linking) VI - 39 IP - 6 DP - 2005 Mar 15 TI - Emission factors and importance of PCDD/Fs, PCBs, PCNs, PAHs and PM10 from the domestic burning of coal and wood in the U.K. PG - 1436-47 AB - This paper presents emission factors (EFs) derived for a range of persistent organic pollutants (POPs) when coal and wood were subject to controlled burning experiments, designed to simulate domestic burning for space heating. A wide range of POPs were emitted, with emissions from coal being higher than those from wood. Highest EFs were obtained for particulate matter, PM10, (approximately 10 g/kg fuel) and polycyclic aromatic hydrocarbons (approximately 100 mg/ kg fuel for sigmaPAHs). For chlorinated compounds, EFs were highest for polychlorinated biphenyls (PCBs), with polychlorinated naphthalenes (PCNs), dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs) being less abundant. EFs were on the order of 1000 ng/kg fuel for sigmaPCBs, 100s ng/ kg fuel for sigmaPCNs and 100 ng/kg fuel for sigmaPCDD/Fs. The study confirmed that mono- to trichlorinated dibenzofurans, Cl1,2,3DFs, were strong indicators of low temperature combustion processes, such as the domestic burning of coal and wood. It is concluded that numerous PCB and PCN congeners are routinely formed during the combustion of solid fuels. However, their combined emissions from the domestic burning of coal and wood would contribute only a few percent to annual U.K. emission estimates. Emissions of PAHs and PM10 were major contributors to U.K. national emission inventories. Major emissions were found from the domestic burning for Cl1,2,3DFs, while the contribution of PCDD/F-sigmaTEQ to total U.K. emissions was minor. FAU - Lee, Robert G M AU - Lee RG AD - Department of Environmental Science, IENS, Lancaster University, Lancaster LA1 4YQ, UK. FAU - Coleman, Peter AU - Coleman P FAU - Jones, Joanne L AU - Jones JL FAU - Jones, Kevin C AU - Jones KC FAU - Lohmann, Rainer AU - Lohmann R LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't PL - United States TA - Environ Sci Technol JT - Environmental science & technology JID - 0213155 RN - 0 (Air Pollutants) RN - 0 (Benzofurans) RN - 0 (Coal) RN - 0 (Dibenzofurans, Polychlorinated) RN - 0 (Environmental Pollutants) RN - 0 (Naphthalenes) RN - 0 (Polychlorinated Dibenzodioxins) RN - 0 (Polycyclic Aromatic Hydrocarbons) RN - DFC2HB4I0K (Polychlorinated Biphenyls) SB - IM MH - Air Pollutants/*analysis MH - Benzofurans/*analysis MH - Coal MH - Dibenzofurans, Polychlorinated MH - Environmental Pollutants/*analysis MH - *Incineration MH - Naphthalenes/*analysis MH - Polychlorinated Biphenyls/*analysis MH - Polychlorinated Dibenzodioxins/*analogs & derivatives/*analysis MH - Polycyclic Aromatic Hydrocarbons/*analysis MH - United Kingdom MH - Wood EDAT- 2005/04/12 09:00 MHDA- 2005/07/26 09:00 CRDT- 2005/04/12 09:00 PHST- 2005/04/12 09:00 [pubmed] PHST- 2005/07/26 09:00 [medline] PHST- 2005/04/12 09:00 [entrez] AID - 10.1021/es048745i [doi] PST - ppublish SO - Environ Sci Technol. 2005 Mar 15;39(6):1436-47. doi: 10.1021/es048745i.