PMID- 15830956
OWN - NLM
STAT- MEDLINE
DCOM- 20050708
LR  - 20190720
IS  - 0021-9673 (Print)
IS  - 0021-9673 (Linking)
VI  - 1069
IP  - 2
DP  - 2005 Apr 1
TI  - Analysis of herbicides in water using temperature-responsive chromatography and 
      an aqueous mobile phase.
PG  - 281-5
AB  - A simple and rapid method has been developed for herbicides in water using 
      temperature-responsive liquid chromatography (LC) and a column packed with 
      poly(N-isopropylacrylamide) (PNIPAAm), a polymer anchored on the stationary-phase 
      surface of modified silica. PNIPAAm reversibly changes its 
      hydrophilic/hydrophobic properties in water in response to temperature. The 
      method was used to determine five sulfonylurea and three urea herbicides. 
      Separation was achieved with a 10 mM ammonium acetate (pH 3.0) isocratic aqueous 
      mobile phase, and by changing the column temperature. The analytes were extracted 
      from water by off-line solid-phase extraction (SPE) with an N-vinyl-pyrrolidone 
      polymer cartridge. The average recoveries of the eight herbicides from spiked 
      pure water, tap water and river water were 70-130% with relative standard 
      deviations (RSDs) of <10%. The limits of quantitation (LOQ) of the eight 
      herbicides were between 1 and 4 microg l(-1).
FAU - Ayano, Eri
AU  - Ayano E
AD  - National Institute of Health Sciences, 1-18-1 Kamiyoga, Setagaya-ku, Tokyo 
      158-8501, Japan.
FAU - Okada, Yuji
AU  - Okada Y
FAU - Sakamoto, Chikako
AU  - Sakamoto C
FAU - Kanazawa, Hideko
AU  - Kanazawa H
FAU - Okano, Teruo
AU  - Okano T
FAU - Ando, Masanori
AU  - Ando M
FAU - Nishimura, Tetsuji
AU  - Nishimura T
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
PL  - Netherlands
TA  - J Chromatogr A
JT  - Journal of chromatography. A
JID - 9318488
RN  - 0 (Acrylic Resins)
RN  - 0 (Herbicides)
RN  - 0 (Phenylurea Compounds)
RN  - 0 (Sulfonylurea Compounds)
RN  - 0 (Water Pollutants, Chemical)
RN  - 25189-55-3 (poly-N-isopropylacrylamide)
SB  - IM
MH  - Acrylic Resins
MH  - Chromatography, Liquid/*methods
MH  - Herbicides/*analysis
MH  - Hydrophobic and Hydrophilic Interactions
MH  - Phenylurea Compounds/analysis
MH  - Reproducibility of Results
MH  - Sulfonylurea Compounds/analysis
MH  - Temperature
MH  - Water Pollutants, Chemical/*analysis
EDAT- 2005/04/16 09:00
MHDA- 2005/07/09 09:00
CRDT- 2005/04/16 09:00
PHST- 2005/04/16 09:00 [pubmed]
PHST- 2005/07/09 09:00 [medline]
PHST- 2005/04/16 09:00 [entrez]
AID - S0021-9673(05)00216-5 [pii]
AID - 10.1016/j.chroma.2005.01.100 [doi]
PST - ppublish
SO  - J Chromatogr A. 2005 Apr 1;1069(2):281-5. doi: 10.1016/j.chroma.2005.01.100.