PMID- 15885412
OWN - NLM
STAT- MEDLINE
DCOM- 20051011
LR  - 20121115
IS  - 0304-3894 (Print)
IS  - 0304-3894 (Linking)
VI  - 121
IP  - 1-3
DP  - 2005 May 20
TI  - A study of kinetic modelling and reaction pathway of 2,4-dichlorophenol 
      transformation by photo-fenton-like oxidation.
PG  - 119-26
AB  - The degradation of 2,4-dichlorophenol (2,4-DCP) by the photo-Fenton-like 
      (Fe3+/H2O2/UVC) process under various reaction conditions was investigated. It 
      was interesting to find that the reaction kinetics of 2,4-DCP in Fe3+/H2O2/UVC 
      systems varied depending on the initial [Fe3+] concentration. A pseudo 
      first-order kinetic and a non-conventional kinetic were discovered at low and 
      higher [Fe3+] concentrations, respectively. A model was used to simulate the 
      non-conventional kinetic process, where two character parameters (the initial 
      decay rate and the final decay fraction) were found to be critical in determining 
      the process. The two parameters successfully quantify the photo-Fenton-like 
      oxidation under different concentrations of [Fe3+] and [H2O2] and the 
      corresponding ratios of Fe(III)/H2O2. The reaction intermediates were identified 
      by an LC/MS analysis and a reaction mechanism was proposed.
FAU - Chu, W
AU  - Chu W
AD  - Department of Civil and Structural Engineering, Research Centre for Environmental 
      Technology and Management, The Hong Kong Polytechnic University, Hunghom, 
      Kowloon, Hong Kong. cewchu@polyu.edu.hk
FAU - Kwan, C Y
AU  - Kwan CY
FAU - Chan, K H
AU  - Chan KH
FAU - Kam, S K
AU  - Kam SK
LA  - eng
PT  - Journal Article
PL  - Netherlands
TA  - J Hazard Mater
JT  - Journal of hazardous materials
JID - 9422688
RN  - 0 (Chlorophenols)
RN  - R669TG1950 (2,4-dichlorophenol)
SB  - IM
MH  - Chlorophenols/*chemistry
MH  - Kinetics
MH  - *Models, Chemical
MH  - Oxidative Phosphorylation
MH  - Photolysis
EDAT- 2005/05/12 09:00
MHDA- 2005/10/12 09:00
CRDT- 2005/05/12 09:00
PHST- 2004/11/30 00:00 [received]
PHST- 2005/01/27 00:00 [revised]
PHST- 2005/01/31 00:00 [accepted]
PHST- 2005/05/12 09:00 [pubmed]
PHST- 2005/10/12 09:00 [medline]
PHST- 2005/05/12 09:00 [entrez]
AID - S0304-3894(05)00052-X [pii]
AID - 10.1016/j.jhazmat.2005.01.019 [doi]
PST - ppublish
SO  - J Hazard Mater. 2005 May 20;121(1-3):119-26. doi: 10.1016/j.jhazmat.2005.01.019.