PMID- 15893335 OWN - NLM STAT- MEDLINE DCOM- 20060801 LR - 20131121 IS - 0025-326X (Print) IS - 0025-326X (Linking) VI - 50 IP - 11 DP - 2005 Nov TI - Chlorinated pesticides and PCBs in the sea-surface microlayer and seawater samples of Singapore. PG - 1233-43 AB - Sea-surface microlayer (SML) and seawater samples collected from Singapore's coastal marine environment were analyzed for selected chlorinated pesticides and polychlorinated biphenyls (PCBs). The SML is a potential site of enrichment of persistent organic pollutants (POPs) compared to the underlying water column. The concentration ranges of SigmaHCH, SigmaDDT and SigmaPCB in subsurface (1 m depth) seawater were 0.4-27.2 ng/l (mean 4.0 ng/l), 0.01-0.6 ng/l (mean 0.1 ng/l) and 0.05-1.8 ng/l (mean 0.5 ng/l) respectively. In the SML, the concentration ranges of SigmaHCH, SigmaDDT and SigmaPCB were 0.6-64.6 ng/l (mean 9.9 ng/l), 0.01-0.7 ng/l (mean 0.2 ng/l) and 0.07-12.4 ng/l (mean 1.3 ng/l) respectively. High spatial and temporal distribution was observed for all POPs measured. However, overall levels measured in the SML were lower than levels reported in the literature for SML samples from temperate coastal regions-possibly due to loss of semi-volatile compounds in the tropical climate of Singapore. Atmospheric wet deposition during the monsoon season may be an important source of POPs to the SML. This study provides the first scientific data on POP concentrations and enrichment factors in the SML for Southeast Asia. FAU - Wurl, Oliver AU - Wurl O AD - Department of Chemical and Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, Singapore 117576, Singapore. g0203875@nus.edu.sg FAU - Obbard, Jeffrey Philip AU - Obbard JP LA - eng PT - Comparative Study PT - Journal Article PT - Research Support, Non-U.S. Gov't PL - England TA - Mar Pollut Bull JT - Marine pollution bulletin JID - 0260231 RN - 0 (Pesticides) RN - 0 (Water Pollutants, Chemical) RN - DFC2HB4I0K (Polychlorinated Biphenyls) SB - IM MH - Environmental Monitoring/*statistics & numerical data MH - Gas Chromatography-Mass Spectrometry MH - Pesticides/*analysis MH - Polychlorinated Biphenyls/*analysis MH - Seawater/*analysis MH - Singapore MH - Water Pollutants, Chemical/*analysis EDAT- 2005/05/17 09:00 MHDA- 2006/08/02 09:00 CRDT- 2005/05/17 09:00 PHST- 2005/05/17 09:00 [pubmed] PHST- 2006/08/02 09:00 [medline] PHST- 2005/05/17 09:00 [entrez] AID - S0025-326X(05)00167-0 [pii] AID - 10.1016/j.marpolbul.2005.04.022 [doi] PST - ppublish SO - Mar Pollut Bull. 2005 Nov;50(11):1233-43. doi: 10.1016/j.marpolbul.2005.04.022.