PMID- 16386361 OWN - NLM STAT- MEDLINE DCOM- 20061026 LR - 20131121 IS - 0304-3894 (Print) IS - 0304-3894 (Linking) VI - 135 IP - 1-3 DP - 2006 Jul 31 TI - AC/O3-BAC processes for removing refractory and hazardous pollutants in raw water. PG - 129-33 AB - Granular activated carbon (AC)/O(3)-biological activated carbon (BAC) process was employed to treat raw water and compared to O(3)-BAC process in its optimum parameters (3 mg/L ozone dosage with 15 min oxidation time and 15 min empty bed contact time in BAC). The results showed that the presence of AC improved ozone utilization and biodegradability of the effluent. For dissolved organic carbon (DOC) removal, AC/O(3)-BAC was more efficient than O(3)-BAC and its synergetic effect could be noticed. It was showed that small molecules with molecular weight (MW)<3 kDa predominated in the raw water accounting for more than 56% DOC, and their amount increased after oxidation, accounting for more than 64% DOC. Except for organic pollutants with MW>10 kDa, those of other MW range were decomposed better by AC/O(3) process than by O(3) process alone. GC/MS analysis showed that AC/O(3)-BAC process was effective in removing phthalate esters (PAEs) and persistent organic pollutants (POPs). PAEs' removal ratio reached more than 93% and reduced with the increase of the length of the alkyl side chains and the alkyl branch chains. POPs-polybromobiphenyls' removal reached more than 94% except for 2,2',4,5',6-pentabromophenyl and decreased with the substitutional bromines increase except for 2,2',5,5'-tetrabromobiphenyl, which could be completely removed. FAU - Li, Laisheng AU - Li L AD - School of Chemistry and Environment, South China Normal University, Guangzhou Higher Education Mega Center, Guangzhou 510006, China. llsh99@mails.tsinghua.edu.cn FAU - Zhu, Wanpeng AU - Zhu W FAU - Zhang, Pengyi AU - Zhang P FAU - Zhang, Qiuyun AU - Zhang Q FAU - Zhang, Zulin AU - Zhang Z LA - eng PT - Journal Article DEP - 20051228 PL - Netherlands TA - J Hazard Mater JT - Journal of hazardous materials JID - 9422688 RN - 0 (Water Pollutants, Chemical) RN - 66H7ZZK23N (Ozone) RN - 7440-44-0 (Carbon) SB - IM MH - Carbon/*chemistry MH - Molecular Weight MH - Ozone/*chemistry MH - *Water Pollutants, Chemical/toxicity MH - Water Purification/*methods EDAT- 2006/01/03 09:00 MHDA- 2006/10/27 09:00 CRDT- 2006/01/03 09:00 PHST- 2005/09/22 00:00 [received] PHST- 2005/10/13 00:00 [revised] PHST- 2005/11/12 00:00 [accepted] PHST- 2006/01/03 09:00 [pubmed] PHST- 2006/10/27 09:00 [medline] PHST- 2006/01/03 09:00 [entrez] AID - S0304-3894(05)00738-7 [pii] AID - 10.1016/j.jhazmat.2005.11.045 [doi] PST - ppublish SO - J Hazard Mater. 2006 Jul 31;135(1-3):129-33. doi: 10.1016/j.jhazmat.2005.11.045. Epub 2005 Dec 28.