PMID- 16471615 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20060814 LR - 20070323 IS - 1520-6106 (Print) IS - 1520-5207 (Linking) VI - 110 IP - 2 DP - 2006 Jan 19 TI - In situ synthesis and characterization of multiwalled carbon nanotube/Au nanoparticle composite materials. PG - 853-7 AB - An effective and facile in situ reduction approach for the fabrication of carbon nanotube-supported Au nanoparticle (CNT/Au NP) composite nanomaterials is demonstrated in this article. Linear polyethyleneimine (PEI) is ingeniously used as both a functionalizing agent for the multiwalled carbon nanotubes (MWNTs) and a reducing agent for the formation of Au NPs. This method involves a simple mixing process followed by a mild heating process. This approach does not need the exhaustive surface oxidation process of CNTs. The coverage of Au NPs on CNTs is tunable by varying the experimental parameters, such as the initial molar ratio of PEI to HAuCl4, the relative concentration of PEI and HAuCl4 to MWNTs, and the temperature and duration of the heat treatment. More importantly, even the heterogeneous CNT/Au composite nanowires are obtainable through this method. TEM, XPS, and XRD are all used to characterize the CNT/Au composite materials. In addition, the optical and electrocatalytic properties are investigated. FAU - Hu, Xiaoge AU - Hu X AD - State Key Laboratory of Electroanalytical Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Graduate School of the Chinese Academy of Science, Changchun, Jilin, 130022, China. FAU - Wang, Tie AU - Wang T FAU - Qu, Xiaohu AU - Qu X FAU - Dong, Shaojun AU - Dong S LA - eng PT - Journal Article PL - United States TA - J Phys Chem B JT - The journal of physical chemistry. B JID - 101157530 EDAT- 2006/02/14 09:00 MHDA- 2006/02/14 09:01 CRDT- 2006/02/14 09:00 PHST- 2006/02/14 09:00 [pubmed] PHST- 2006/02/14 09:01 [medline] PHST- 2006/02/14 09:00 [entrez] AID - 10.1021/jp055834o [doi] PST - ppublish SO - J Phys Chem B. 2006 Jan 19;110(2):853-7. doi: 10.1021/jp055834o.