PMID- 16573044 OWN - NLM STAT- MEDLINE DCOM- 20060712 LR - 20190715 IS - 1533-4880 (Print) IS - 1533-4880 (Linking) VI - 6 IP - 2 DP - 2006 Feb TI - Optically active poly(dimethylsiloxane) elastomer films through doping with gold nanoparticles. PG - 453-8 AB - Poly(dimethylsiloxane) (PDMS) elastomer films synthesized through a cross-linking reaction between hydroxyl-terminated or vinyl-terminated PDMS have been homogeneously doped with silica-coated Au nanoparticles. The nanocomposite synthesis involves mixing a preformed colloid of surface-modified metal nanoparticles with the elastomer film precursors. The homogeneous distribution of nanoparticles is demonstrated through the presence of well defined plasmon absorbance bands in the visible, which clearly show that the composites retain the characteristic optical properties of single Au nanoparticles. The metal particle concentration could be easily tailored either through the amount or the concentration of the nanoparticle colloid added. Since the Au nanoparticles are not cross-linked to the polymer and the concentration of particles is relatively low, we postulate that the presence of the nanoparticles does not affect the mechanical properties of the films, though this remains to be confirmed. FAU - Pastoriza-Santos, Isabel AU - Pastoriza-Santos I AD - Departamento de Quimica Fisica, Universidade de Vigo, 36310 Vigo, Spain. FAU - Perez-Juste, Jorge AU - Perez-Juste J FAU - Kickelbick, Guido AU - Kickelbick G FAU - Liz-Marzan, Luis M AU - Liz-Marzan LM LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't PL - United States TA - J Nanosci Nanotechnol JT - Journal of nanoscience and nanotechnology JID - 101088195 RN - 0 (Dimethylpolysiloxanes) RN - 0 (Silicones) RN - 63148-62-9 (baysilon) RN - 7440-57-5 (Gold) SB - IM MH - Dimethylpolysiloxanes/*chemistry MH - Gold/*chemistry MH - *Nanotechnology MH - Silicones/*chemistry EDAT- 2006/04/01 09:00 MHDA- 2006/07/13 09:00 CRDT- 2006/04/01 09:00 PHST- 2006/04/01 09:00 [pubmed] PHST- 2006/07/13 09:00 [medline] PHST- 2006/04/01 09:00 [entrez] AID - 10.1166/jnn.2006.922 [doi] PST - ppublish SO - J Nanosci Nanotechnol. 2006 Feb;6(2):453-8. doi: 10.1166/jnn.2006.922.