PMID- 16768534 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20070720 LR - 20060613 IS - 0743-7463 (Print) IS - 0743-7463 (Linking) VI - 22 IP - 13 DP - 2006 Jun 20 TI - Ink dependence of poly(dimethylsiloxane) contamination in microcontact printing. PG - 5945-51 AB - Poly(dimethylsiloxane) (PDMS) is the most widely used stamp material in microcontact printing. It has excellent properties with respect to versatility, chemical inertness, and mechanical stability. However, it has an inclination to contaminate printed substrates with low molecular weight siloxane fragments. In this study, it is shown, by a combination of lateral force microscopy, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy, that the extent of the PDMS-induced contamination is dependent on the nature of the ink used. The highest degree of contamination was found for relatively polar inks, whereas apolar alkanethiol inks were found to shield the substrate from contamination. This is interpreted in terms of the contaminating species being polar in nature. FAU - Sharpe, Ruben B A AU - Sharpe RB AD - MESA+ Institute for Nanotechnology and Faculty of Science and Technology, University of Twente, P.O. Box 217, 7500 AE Enschede, The Netherlands. FAU - Burdinski, Dirk AU - Burdinski D FAU - van der Marel, Cees AU - van der Marel C FAU - Jansen, Jan A J AU - Jansen JA FAU - Huskens, Jurriaan AU - Huskens J FAU - Zandvliet, Harold J W AU - Zandvliet HJ FAU - Reinhoudt, David N AU - Reinhoudt DN FAU - Poelsema, Bene AU - Poelsema B LA - eng PT - Journal Article PL - United States TA - Langmuir JT - Langmuir : the ACS journal of surfaces and colloids JID - 9882736 EDAT- 2006/06/14 09:00 MHDA- 2006/06/14 09:01 CRDT- 2006/06/14 09:00 PHST- 2006/06/14 09:00 [pubmed] PHST- 2006/06/14 09:01 [medline] PHST- 2006/06/14 09:00 [entrez] AID - 10.1021/la053298l [doi] PST - ppublish SO - Langmuir. 2006 Jun 20;22(13):5945-51. doi: 10.1021/la053298l.