PMID- 16786492 OWN - NLM STAT- MEDLINE DCOM- 20061218 LR - 20191210 IS - 1526-498X (Print) IS - 1526-498X (Linking) VI - 62 IP - 9 DP - 2006 Sep TI - Analytical method for assessing potential dermal exposure to captan, using whole body dosimetry, in small vegetable production units in Argentina. PG - 811-8 AB - An analytical method has been developed that can be used to determine the potential dermal exposure (PDE) of workers to the pesticide captan in small-scale horticultural production units. The methodology is based on the whole body dosimetry technique, using a cotton coverall and cotton gloves as sampling media, with protective clothing worn beneath the cotton media to protect the operator. The quantitative determination of captan was done by gas chromatography-electron capture detector (GC-ECD), with the analytical method validated by measuring limits of detection and quantification, linear ranges, sample recovery and precision. Special emphasis is placed on factors that affected the stability of captan during chromatographic determination. The data generated for potential dermal exposure are presented separately for mixing/loading and application activities. These data are compared with values obtained with visible tracers using a similar field technique. Margin of safety (MOS) values are also calculated for the agricultural procedures studied. CI - Copyright 2006 Society of Chemical Industry. FAU - Hughes, Enrique A AU - Hughes EA AD - Instituto de Ciencias, Universidad Nacional de General Sarmiento (UNGS), J. M. Gutierrez 1150, Los Polvorines, (B1613GSX), Argentina. FAU - Zalts, Anita AU - Zalts A FAU - Ojeda, Javier J AU - Ojeda JJ FAU - Flores, Andrea P AU - Flores AP FAU - Glass, Richard C AU - Glass RC FAU - Montserrat, Javier M AU - Montserrat JM LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't PT - Validation Study PL - England TA - Pest Manag Sci JT - Pest management science JID - 100898744 RN - 0 (Fungicides, Industrial) RN - EOL5G26Q9F (Captan) SB - IM MH - *Agriculture MH - Argentina MH - Captan/*analysis MH - Chromatography, Gas/*methods MH - Dermis/*chemistry MH - Environmental Monitoring/*methods MH - Fungicides, Industrial/*analysis MH - Humans MH - Occupational Exposure/*analysis MH - Protective Clothing MH - Risk Assessment/methods MH - Spectrophotometry/methods MH - Vegetables EDAT- 2006/06/21 09:00 MHDA- 2006/12/19 09:00 CRDT- 2006/06/21 09:00 PHST- 2006/06/21 09:00 [pubmed] PHST- 2006/12/19 09:00 [medline] PHST- 2006/06/21 09:00 [entrez] AID - 10.1002/ps.1232 [doi] PST - ppublish SO - Pest Manag Sci. 2006 Sep;62(9):811-8. doi: 10.1002/ps.1232.