PMID- 16843475
OWN - NLM
STAT- MEDLINE
DCOM- 20061122
LR  - 20131121
IS  - 0021-9673 (Print)
IS  - 0021-9673 (Linking)
VI  - 1129
IP  - 1
DP  - 2006 Sep 29
TI  - Simultaneous determination of aliphatic and aromatic amines in water and sediment 
      samples by ion-pair extraction and gas chromatography-mass spectrometry.
PG  - 88-94
AB  - A gas chromatography-mass spectrometry (GC-MS) method has been proposed for the 
      determination of aliphatic and aromatic amines in a variety of environmental 
      samples including wastewater, river water, sea water and sediment samples. The 
      method includes ion-pair extraction with bis-2-ethylhexylphosphate (BEHPA), 
      derivatisation of compounds with isobutyl chloroformate (IBCF) and their GC-MS 
      analysis. Aliphatic and aromatic amines were isolated from aqueous samples using 
      BEHPA as ion-pair reagent and derivatised with IBCF for their chromatographic 
      analysis. Solid-liquid extraction of aliphatic and aromatic amines in sediment 
      samples were performed in Soxhlet apparatus with acidic MeOH and ion-pair 
      extraction with BEHPA were carried out for the isolation of amines followed by 
      derivatisation with IBCF. Aliphatic and aromatic amines were then analysed with 
      GC-MS in both electron impact (EI) and positive and negative ion chemical 
      ionisation (PNICI) mode as their isobutyloxycarbonyl (isoBOC) derivatives. The 
      obtained recoveries ranged from 81.0 to 98.0% and the precision of this method, 
      as indicated by the relative standard deviations (RSDs) was within the range of 
      0.5 and 4.3%. The detection limits obtained from calculations by using GC-MS 
      results based on S/N = 3 were within the range from 0.07 to 0.50 ng/l.
FAU - Akyuz, Mehmet
AU  - Akyuz M
AD  - Zonguldak Karaelmas University, Faculty of Sciences and Letters, Department of 
      Chemistry, 67100 Zonguldak, Turkey. makyuz2004@yahoo.co.uk
FAU - Ata, Sevket
AU  - Ata S
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20060714
PL  - Netherlands
TA  - J Chromatogr A
JT  - Journal of chromatography. A
JID - 9318488
RN  - 0 (Amines)
RN  - 0 (Water Pollutants, Chemical)
RN  - 059QF0KO0R (Water)
SB  - IM
MH  - Amines/*analysis
MH  - Gas Chromatography-Mass Spectrometry/*methods
MH  - Geologic Sediments/*analysis/chemistry
MH  - Reproducibility of Results
MH  - Water/*analysis/chemistry
MH  - Water Pollutants, Chemical/analysis
EDAT- 2006/07/18 09:00
MHDA- 2006/12/09 09:00
CRDT- 2006/07/18 09:00
PHST- 2006/03/17 00:00 [received]
PHST- 2006/06/14 00:00 [revised]
PHST- 2006/06/22 00:00 [accepted]
PHST- 2006/07/18 09:00 [pubmed]
PHST- 2006/12/09 09:00 [medline]
PHST- 2006/07/18 09:00 [entrez]
AID - S0021-9673(06)01255-6 [pii]
AID - 10.1016/j.chroma.2006.06.075 [doi]
PST - ppublish
SO  - J Chromatogr A. 2006 Sep 29;1129(1):88-94. doi: 10.1016/j.chroma.2006.06.075. 
      Epub 2006 Jul 14.