PMID- 16919310 OWN - NLM STAT- MEDLINE DCOM- 20070130 LR - 20131121 IS - 0045-6535 (Print) IS - 0045-6535 (Linking) VI - 65 IP - 11 DP - 2006 Dec TI - Organochlorine pesticides and polychlorinated biphenyls in soil and water samples in the Northeastern part of Sao Paulo State, Brazil. PG - 1949-58 AB - Detailed analyses of persistent organic pollutants (POPs) such as organochlorine pesticides (OCPs), hexachlorocyclohexane (HCH) isomers (HCHs), dichlorodiphenyltrichloro ethane (DDT) and its metabolites (DDTs) and congeners of polychlorinated biphenyls (PCBs) in soil and surface water from the northeastern Sao Paulo, Brazil allowed the evaluation of the contamination status, distribution and possible pollution sources. The pesticides and PCBs demonstrated markedly different distributions, reflecting different agricultural, domestic and industrial usage in each region studied. The ranges of HCH, DDT, and PCBs concentrations in the soil samples were 0.05-0.92, 0.12-11.01, 0.02-0.25 ng g(-1) dry wt, respectively, and in the surface water samples were 0.02-0.6, 0.02-0.58 and 0.02-0.5 ng l(-1), respectively. Overall elevated levels of DDT and PCB were recorded in region 2, a site very close to melting, automotive batteries industries, and agricultural practice regions. High ratios of metabolites of DDT to DDT isomers revealed the recent use of DDT in this environment. The sources of contamination are closely related to human activities, such as domestic and industrial discharge, street runoff, agricultural pesticides and soil erosion, due to deforestation as well as atmospheric transport. FAU - Rissato, Sandra R AU - Rissato SR AD - Department of Chemistry, Paulista State University (UNESP), P.O. Box 473, 17033-360 Bauru, SP, Brazil. srissato@fc.unesp.br FAU - Galhiane, Mario S AU - Galhiane MS FAU - Ximenes, Valdecir F AU - Ximenes VF FAU - de Andrade, Rita M B AU - de Andrade RM FAU - Talamoni, Jandira L B AU - Talamoni JL FAU - Libanio, Marcelo AU - Libanio M FAU - de Almeida, Marcos V AU - de Almeida MV FAU - Apon, Benhard M AU - Apon BM FAU - Cavalari, Aline A AU - Cavalari AA LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20060817 PL - England TA - Chemosphere JT - Chemosphere JID - 0320657 RN - 0 (Pesticides) RN - 0 (Soil Pollutants) RN - 0 (Water Pollutants, Chemical) RN - DFC2HB4I0K (Polychlorinated Biphenyls) SB - IM MH - Brazil MH - Gas Chromatography-Mass Spectrometry MH - Pesticides/*analysis MH - Polychlorinated Biphenyls/*analysis MH - Sensitivity and Specificity MH - Soil Pollutants/*analysis MH - Water Pollutants, Chemical EDAT- 2006/08/22 09:00 MHDA- 2007/01/31 09:00 CRDT- 2006/08/22 09:00 PHST- 2005/11/02 00:00 [received] PHST- 2006/07/06 00:00 [revised] PHST- 2006/07/06 00:00 [accepted] PHST- 2006/08/22 09:00 [pubmed] PHST- 2007/01/31 09:00 [medline] PHST- 2006/08/22 09:00 [entrez] AID - S0045-6535(06)00872-1 [pii] AID - 10.1016/j.chemosphere.2006.07.011 [doi] PST - ppublish SO - Chemosphere. 2006 Dec;65(11):1949-58. doi: 10.1016/j.chemosphere.2006.07.011. Epub 2006 Aug 17.