PMID- 16968021 OWN - NLM STAT- MEDLINE DCOM- 20061025 LR - 20200930 IS - 1530-6984 (Print) IS - 1530-6984 (Linking) VI - 6 IP - 9 DP - 2006 Sep TI - Bioinspired detection of light using a porphyrin-sensitized single-wall nanotube field effect transistor. PG - 2031-6 AB - Single-wall carbon nanotube (SWNT) field effect transistors (FETs), functionalized noncovalently with a zinc porphyrin derivative, were used to directly detect a photoinduced electron transfer (PET) within a donor/acceptor (D/A) system. We report here that the SWNTs act as the electron donor and the porphyrin molecules as the electron acceptor. The magnitude of the PET was measured to be a function of both the wavelength and intensity of applied light, with a maximum value of 0.37 electrons per porphyrin for light at 420 nm and 100 W/m2. A complete understanding of the photophysics of this D/A system is necessary, as it may form the basis for applications in artificial photosynthesis and alternative energy sources such as solar cells. FAU - Hecht, David S AU - Hecht DS AD - Department of Physics, California NanoSystems Institute, University of California, Los Angeles, California 90095, USA. FAU - Ramirez, Robert J A AU - Ramirez RJ FAU - Briman, Mikhail AU - Briman M FAU - Artukovic, Erika AU - Artukovic E FAU - Chichak, Kelly S AU - Chichak KS FAU - Stoddart, J Fraser AU - Stoddart JF FAU - Gruner, George AU - Gruner G LA - eng PT - Evaluation Study PT - Journal Article PT - Research Support, Non-U.S. Gov't PT - Research Support, U.S. Gov't, Non-P.H.S. PL - United States TA - Nano Lett JT - Nano letters JID - 101088070 RN - 0 (Porphyrins) SB - IM MH - Biomimetics/*methods MH - Electric Conductivity MH - Equipment Design MH - Equipment Failure Analysis MH - Light MH - Materials Testing MH - Nanotubes/*chemistry/radiation effects/ultrastructure MH - Photochemistry/*methods MH - *Photosynthesis MH - Porphyrins/*chemistry/radiation effects MH - Radiation Dosage MH - Transducers MH - *Transistors, Electronic EDAT- 2006/09/14 09:00 MHDA- 2006/10/26 09:00 CRDT- 2006/09/14 09:00 PHST- 2006/09/14 09:00 [pubmed] PHST- 2006/10/26 09:00 [medline] PHST- 2006/09/14 09:00 [entrez] AID - 10.1021/nl061231s [doi] PST - ppublish SO - Nano Lett. 2006 Sep;6(9):2031-6. doi: 10.1021/nl061231s.