PMID- 17010510
OWN - NLM
STAT- MEDLINE
DCOM- 20070604
LR  - 20070320
IS  - 0304-3894 (Print)
IS  - 0304-3894 (Linking)
VI  - 142
IP  - 1-2
DP  - 2007 Apr 2
TI  - Diffusion and solubility coefficients determined by permeation and immersion 
      experiments for organic solvents in HDPE geomembrane.
PG  - 227-35
AB  - The chemical resistance of eight organic solvents in high density polyethylene 
      (HDPE) geomembrane has been investigated using the ASTM F739 permeation method 
      and the immersion test at different temperatures. The diffusion of the 
      experimental organic solvents in HDPE geomembrane was non-Fickian kinetic, and 
      the solubility coefficients can be consistent with the solubility parameter 
      theory. The diffusion coefficients and solubility coefficients determined by the 
      ASTM F739 method were significantly correlated to the immersion tests (p<0.001). 
      The steady state permeation rates also showed a good agreement between ASTM F739 
      and immersion experiments (r(2)=0.973, p<0.001). Using a one-dimensional 
      diffusion equation based on Fick's second law, the diffusion and solubility 
      coefficients obtained by immersion test resulted in over estimates of the ASTM 
      F739 permeation results. The modeling results indicated that the diffusion and 
      solubility coefficients should be obtained using ASTM F739 method which closely 
      simulates the practical application of HDPE as barriers in the field.
FAU - Chao, Keh-Ping
AU  - Chao KP
AD  - Department of Occupational Safety & Health, China Medical University, 91 
      Hsueh-Shih Road, Taichung, Taiwan 40402, ROC. kpchao@mail.cmu.edu.tw
FAU - Wang, Ping
AU  - Wang P
FAU - Wang, Ya-Ting
AU  - Wang YT
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20060818
PL  - Netherlands
TA  - J Hazard Mater
JT  - Journal of hazardous materials
JID - 9422688
RN  - 0 (Membranes, Artificial)
RN  - 0 (Organic Chemicals)
RN  - 0 (Solvents)
RN  - 9002-88-4 (Polyethylene)
SB  - IM
MH  - Diffusion
MH  - Kinetics
MH  - *Membranes, Artificial
MH  - Organic Chemicals/*chemistry
MH  - Polyethylene/*chemistry
MH  - Solubility
MH  - Solvents/*chemistry
MH  - Temperature
EDAT- 2006/10/03 09:00
MHDA- 2007/06/05 09:00
CRDT- 2006/10/03 09:00
PHST- 2005/11/16 00:00 [received]
PHST- 2006/03/30 00:00 [revised]
PHST- 2006/08/04 00:00 [accepted]
PHST- 2006/10/03 09:00 [pubmed]
PHST- 2007/06/05 09:00 [medline]
PHST- 2006/10/03 09:00 [entrez]
AID - S0304-3894(06)00934-4 [pii]
AID - 10.1016/j.jhazmat.2006.08.022 [doi]
PST - ppublish
SO  - J Hazard Mater. 2007 Apr 2;142(1-2):227-35. doi: 10.1016/j.jhazmat.2006.08.022. 
      Epub 2006 Aug 18.