PMID- 17063868 OWN - NLM STAT- MEDLINE DCOM- 20061204 LR - 20191210 IS - 1096-2247 (Print) IS - 1096-2247 (Linking) VI - 56 IP - 10 DP - 2006 Oct TI - Performance and diagnostic evaluation of ozone predictions by the Eta-Community Multiscale Air Quality Forecast System during the 2002 New England Air Quality Study. PG - 1459-71 AB - A real-time air quality forecasting system (Eta-Community Multiscale Air Quality [CMAQ] model suite) has been developed by linking the National Centers for Environmental Estimation Eta model to the U.S. Environmental Protection Agency (EPA) CMAQ model. This work presents results from the application of the Eta-CMAQ modeling system for forecasting ozone (O3) over the Northeastern United States during the 2002 New England Air Quality Study (NEAQS). Spatial and temporal performance of the Eta-CMAQ model for O3 was evaluated by comparison with observations from the EPA Air Quality System (AQS) network. This study also examines the ability of the model to simulate the processes governing the distributions of tropospheric O3 on the basis of the intensive datasets obtained at the four Atmospheric Investigation, Regional Modeling, Analysis, and Estimation (AIRMAP) and Harvard Forest (HF) surface sites. The episode analysis reveals that the model captured the buildup of O3 concentrations over the northeastern domain from August 11 and reproduced the spatial distributions of observed O3 very well for the daytime (8:00 p.m.) of both August 8 and 12 with most of normalized mean bias (NMB) within +/- 20%. The model reproduced 53.3% of the observed hourly O3 within a factor of 1.5 with NMB of 29.7% and normalized mean error of 46.9% at the 342 AQS sites. The comparison of modeled and observed lidar O3 vertical profiles shows that whereas the model reproduced the observed vertical structure, it tended to overestimate at higher altitude. The model reproduced 64-77% of observed NO2 photolysis rate values within a factor of 1.5 at the AIRMAP sites. At the HF site, comparison of modeled and observed O3/nitrogen oxide (NOx) ratios suggests that the site is mainly under strongly NOx-sensitive conditions (>53%). It was found that the modeled lower limits of the O3 production efficiency values (inferred from O3-CO correlation) are close to the observations. FAU - Yu, Shaocai AU - Yu S AD - Atmospheric Sciences Modeling Division, National Exposure Research Laboratory, U.S. Environmental Protection Agency, Research Triangle Park, NC 27711, USA. yu.shaocai@epa.gov FAU - Mathur, Rohit AU - Mathur R FAU - Kang, Daiwen AU - Kang D FAU - Schere, Kenneth AU - Schere K FAU - Eder, Brian AU - Eder B FAU - Pleim, Jonathan AU - Pleim J LA - eng PT - Evaluation Study PT - Journal Article PT - Research Support, U.S. Gov't, Non-P.H.S. PL - United States TA - J Air Waste Manag Assoc JT - Journal of the Air & Waste Management Association (1995) JID - 9503111 RN - 0 (Air Pollutants) RN - 0UZA3422Q4 (Sulfur Dioxide) RN - 66H7ZZK23N (Ozone) RN - 7U1EE4V452 (Carbon Monoxide) SB - IM MH - Air Pollutants/*analysis MH - Carbon Monoxide/analysis MH - Environmental Monitoring MH - Forecasting MH - *Models, Theoretical MH - New England MH - Ozone/*analysis MH - Sulfur Dioxide/analysis EDAT- 2006/10/27 09:00 MHDA- 2006/12/09 09:00 CRDT- 2006/10/27 09:00 PHST- 2006/10/27 09:00 [pubmed] PHST- 2006/12/09 09:00 [medline] PHST- 2006/10/27 09:00 [entrez] AID - 10.1080/10473289.2006.10464554 [doi] PST - ppublish SO - J Air Waste Manag Assoc. 2006 Oct;56(10):1459-71. doi: 10.1080/10473289.2006.10464554.