PMID- 17139487
OWN - NLM
STAT- MEDLINE
DCOM- 20070319
LR  - 20160512
IS  - 1618-2642 (Print)
IS  - 1618-2642 (Linking)
VI  - 387
IP  - 2
DP  - 2007 Jan
TI  - Sensitive measurement of ultratrace phenols in natural water by purge-and-trap 
      with in situ acetylation coupled with gas chromatography-mass spectrometry.
PG  - 687-94
AB  - A novel purge-and-trap method coupled with gas chromatography-mass spectrometry 
      (GC-MS) is developed for the analysis of trace and ultratrace phenols based on 
      their derivatization with acetic anhydride. Parameters affecting the extraction 
      efficiency, such as purge temperature, concentration of sodium chloride, purge 
      time, and volume of derivatization reagent, were investigated. The optimized 
      conditions were addition of 150 microL acetic anhydride, purge time of 25 min at 
      the purge temperature of 60 degrees C with 30% NaCl. The linear range was 0.2-100 
      microg L(-1) for phenols. The limits of detection (LODs) ranged from 0.08 to 0.15 
      microg L(-1) and the relative standard deviations (RSDs) for most of the phenols 
      at the 10 microg L(-1) level were below 10%. Natural water samples collected from 
      a pool were successfully analyzed using the proposed method. The recovery of 
      spiked water samples was 72.9-84.2%.
FAU - Zhao, Ru-Song
AU  - Zhao RS
AD  - Key Laboratory of Bioorganic Phosphorus Chemistry and Chemical Biology, Ministry 
      of Education, Department of Chemistry, Tsinghua University, Beijing, 100084, 
      People's Republic of China. zrswangx@yahoo.com.cn
FAU - Cheng, Chuan-Ge
AU  - Cheng CG
FAU - Yuan, Jin-Peng
AU  - Yuan JP
FAU - Jiang, Ting
AU  - Jiang T
FAU - Wang, Xia
AU  - Wang X
FAU - Lin, Jin-Ming
AU  - Lin JM
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20061201
PL  - Germany
TA  - Anal Bioanal Chem
JT  - Analytical and bioanalytical chemistry
JID - 101134327
RN  - 0 (Phenols)
RN  - 0 (Water Pollutants)
SB  - IM
MH  - Acetylation
MH  - Gas Chromatography-Mass Spectrometry/*methods/standards
MH  - Methods
MH  - Phenols/*analysis
MH  - Reference Standards
MH  - Sensitivity and Specificity
MH  - Water Pollutants/*analysis
EDAT- 2006/12/02 09:00
MHDA- 2007/03/21 09:00
CRDT- 2006/12/02 09:00
PHST- 2006/05/11 00:00 [received]
PHST- 2006/10/02 00:00 [accepted]
PHST- 2006/09/24 00:00 [revised]
PHST- 2006/12/02 09:00 [pubmed]
PHST- 2007/03/21 09:00 [medline]
PHST- 2006/12/02 09:00 [entrez]
AID - 10.1007/s00216-006-0890-7 [doi]
PST - ppublish
SO  - Anal Bioanal Chem. 2007 Jan;387(2):687-94. doi: 10.1007/s00216-006-0890-7. Epub 
      2006 Dec 1.