PMID- 17161419 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20070413 LR - 20091111 IS - 0021-9797 (Print) IS - 0021-9797 (Linking) VI - 307 IP - 1 DP - 2007 Mar 1 TI - Self-assembly of acridine orange dye at a mica/solution interface: formation of nanostripe supramolecular architectures. PG - 272-9 AB - Optical waveguide spectroscopy and atomic force microscopy (AFM) have been used to characterize the supramolecular architectures of acridine orange (AO) dye self-assembled at a mica/aqueous solution interface. Under the saturated adsorption conditions, optical waveguide spectroscopy revealed that the dye formed H-type aggregates at the interface. In situ AFM visualized interesting morphology of the dye aggregates showing nanosized meandering stripes with the width of approximately 1.5 nm (or brightness periodicity of approximately 3 nm). Electrostatic adsorption of the dye cations onto a mica surface as well as the intermolecular pi-pi stacking brought about the ordered nanostructures. We propose an interfacial aggregation model that shows a meandering staircase structure with the intermolecular slip angle of 60 degrees. According to the model, the AO molecule occupies a surface area of about 1.0 nm2. FAU - Yao, Hiroshi AU - Yao H AD - Graduate School of Material Science, University of Hyogo, 3-2-1 Koto, Kamigori-cho, Ako-gun, Hyogo 678-1297, Japan. yao@sci.u-hyogo.ac.jp FAU - Kobayashi, Shogo AU - Kobayashi S FAU - Kimura, Keisaku AU - Kimura K LA - eng PT - Journal Article DEP - 20061129 PL - United States TA - J Colloid Interface Sci JT - Journal of colloid and interface science JID - 0043125 EDAT- 2006/12/13 09:00 MHDA- 2006/12/13 09:01 CRDT- 2006/12/13 09:00 PHST- 2006/07/27 00:00 [received] PHST- 2006/11/06 00:00 [revised] PHST- 2006/11/26 00:00 [accepted] PHST- 2006/12/13 09:00 [pubmed] PHST- 2006/12/13 09:01 [medline] PHST- 2006/12/13 09:00 [entrez] AID - S0021-9797(06)01101-5 [pii] AID - 10.1016/j.jcis.2006.11.030 [doi] PST - ppublish SO - J Colloid Interface Sci. 2007 Mar 1;307(1):272-9. doi: 10.1016/j.jcis.2006.11.030. Epub 2006 Nov 29.