PMID- 17174025 OWN - NLM STAT- MEDLINE DCOM- 20070927 LR - 20070625 IS - 0304-3894 (Print) IS - 0304-3894 (Linking) VI - 145 IP - 3 DP - 2007 Jul 16 TI - Effects of pH and temperature on isotherm parameters of chlorophenols biosorption to anaerobic granular sludge. PG - 398-403 AB - As the most important parameters affecting the biosorption, pH and temperature were studied in this paper in order to more completely understand their effects on chlorophenols' biosorption onto anaerobic granular sludge. Sorption isotherms of 4-chlorophenol (4-CP) and 2,4-dichlorophenol (2,4-DCP) at various temperatures were determined; the data of 4-CP could be simulated by Langmuir model, while the data of 2,4-DCP could only be reproduced by Freudlich equation. The uptake capacity of 4-CP and 2,4-DCP could reach 1.5mgg(-1) and 5.04mgg(-1) when 2,4-DCP concentration was 90mgL(-1) and 4-CP concentration was 107mgL(-1), respectively. 2,4-DCP was more strongly adsorbed onto the anaerobic granular sludge than 4-CP, which might be correlated with the numbers of chlorine substitute. The Experiments studying pH effects showed that the adsorption capacity of 4-CP and 2,4-DCP was quite pH dependent and increased with decrease in pH. FAU - Gao, Ruiying AU - Gao R AD - Laboratory of Environmental Technology, INET, Tsinghua University, Beijing 100084, China. FAU - Wang, Jianlong AU - Wang J LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20061119 PL - Netherlands TA - J Hazard Mater JT - Journal of hazardous materials JID - 9422688 RN - 0 (Chlorophenols) RN - 0 (Industrial Waste) RN - 0 (Water Pollutants, Chemical) SB - IM MH - Adsorption MH - Anaerobiosis MH - Bacteria, Anaerobic/physiology MH - Chlorophenols/*chemistry MH - Hydrogen-Ion Concentration MH - *Industrial Waste MH - Temperature MH - Waste Management/*methods MH - Water Pollutants, Chemical/*chemistry EDAT- 2006/12/19 09:00 MHDA- 2007/09/28 09:00 CRDT- 2006/12/19 09:00 PHST- 2006/07/15 00:00 [received] PHST- 2006/09/30 00:00 [revised] PHST- 2006/11/15 00:00 [accepted] PHST- 2006/12/19 09:00 [pubmed] PHST- 2007/09/28 09:00 [medline] PHST- 2006/12/19 09:00 [entrez] AID - S0304-3894(06)01396-3 [pii] AID - 10.1016/j.jhazmat.2006.11.036 [doi] PST - ppublish SO - J Hazard Mater. 2007 Jul 16;145(3):398-403. doi: 10.1016/j.jhazmat.2006.11.036. Epub 2006 Nov 19.