PMID- 17260763
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20100514
LR  - 20070130
IS  - 1000-0593 (Print)
IS  - 1000-0593 (Linking)
VI  - 26
IP  - 11
DP  - 2006 Nov
TI  - [Study on the determination of multicomponent pesticide residual based on 
      synchronous-derivative fluorimetry].
PG  - 2085-8
AB  - In the multicomponent fluorescence measurement of pesticide residual, the 
      comparability of construction and chemical property among the components leads to 
      the overlap of the fluorescence spectra, so it's very difficult to do 
      simultaneous measurment with conventional fluorescent spectroscopy. Using 
      synchronous-derivative fluorimetry, the fluorescence spectra of carbaryl and 
      carbofuran and the effect of different pH on the pesticides were studied, with pH 
      7.8, and delta lamda=60 nm, synchronous fluorescence scan of the mixed solution 
      in the wavelength range of 250-450 nm, was carried out, and transformed to first 
      order derivative fluorescence spectrum. The experiment results indicate that 
      their synchronous-derivative fluorescence spectra were separated absolutely, 
      eliminating the disturbance between them; the fixed solution can be measured 
      simultaneity. For carbaryl and carbofuran, the linear range is 0. 013-1.156 
      microg x mL(-1) and 0.025-1.042 microg x mL(-1), the detection limit is 0.013 
      micorg x mL(-1) and 0.025 microg x mL(-1), and the average recovery is 98%-104% 
      and 96%-103%, respectively. The relative standard deviations (RSDs) of them are 
      all under 2.25%.
FAU - Wang, Yu-tian
AU  - Wang YT
AD  - College of Electrical Engineering, Yanshan University, Qinhuangdao 066004, China.
FAU - Cui, Li-chao
AU  - Cui LC
FAU - Wang, Dong-sheng
AU  - Wang DS
FAU - Li, Yan-chun
AU  - Li YC
LA  - chi
PT  - English Abstract
PT  - Journal Article
PL  - China
TA  - Guang Pu Xue Yu Guang Pu Fen Xi
JT  - Guang pu xue yu guang pu fen xi = Guang pu
JID - 9424805
EDAT- 2007/01/31 09:00
MHDA- 2007/01/31 09:01
CRDT- 2007/01/31 09:00
PHST- 2007/01/31 09:00 [pubmed]
PHST- 2007/01/31 09:01 [medline]
PHST- 2007/01/31 09:00 [entrez]
PST - ppublish
SO  - Guang Pu Xue Yu Guang Pu Fen Xi. 2006 Nov;26(11):2085-8.