PMID- 17288154
OWN - NLM
STAT- MEDLINE
DCOM- 20100603
LR  - 20161018
IS  - 1000-8713 (Print)
IS  - 1000-8713 (Linking)
VI  - 24
IP  - 6
DP  - 2006 Nov
TI  - [Simultaneous determination of triazine herbicide residues in maize by gas 
      chromatography].
PG  - 648-51
AB  - A gas chromatographic method was developed for the determination of simeton, 
      simazine, atrazine, propazine, terbumeton, terbuthylazine, cyprazine, simetryn, 
      prometryn, terbutryn, methoprotryne, hexazinone residues in maize. The triazine 
      herbicide residues were extracted with acetonitrile by blender and then cleaned 
      up on a strong cation-exchange (SCX) solid-phase extraction cartridge. The SCX 
      cartridge was conditioned with acetone, methylene chloride, washed with methylene 
      chloride, acetone and eluted with methanol-water (9: 1, v/v) solution saturated 
      potassium chloride. As a result, most interfering impurities were removed in the 
      SPE cleanup procedure. The gas chromatographic analysis was performed on a 
      capillary column (DB-5, 30 m x 0.25 mm i. d. x 0.25 microm) and determined by 
      nitrogen phosphorus detector (NPD). Twelve triazine herbicides were effectively 
      separated on this column. Diazinon was used as the internal standard for the 
      determination. Linear correlation coefficients of the 12 herbicides were higher 
      than 0.998 in the range of 0.01 to 2.0 mg/L. The limits of quantitation of the 
      method were 0.01 mg/kg for these compounds. Average recoveries of these 
      herbicides from spiked samples ranged from 84.0% to 106.8% at fortification 
      levels of 0.01 - 0.5 mg/kg and the relative standard deviations (RSDs) were 
      between 0.9% and 4.7%. The method is suitable for the simultaneous determination 
      of a wide range of triazine herbicides in maize in commodities inspection.
FAU - Zhang, Jingbo
AU  - Zhang J
AD  - Dalian University of Technology, Dalian 116024, China. zhangjb110@yahoo.com.cn
FAU - Jiang, Wenfeng
AU  - Jiang W
FAU - Dong, Zhenlin
AU  - Dong Z
FAU - Zhao, Shoucheng
AU  - Zhao S
FAU - Wei, Feng
AU  - Wei F
LA  - chi
PT  - English Abstract
PT  - Journal Article
PL  - China
TA  - Se Pu
JT  - Se pu = Chinese journal of chromatography
JID - 9424804
RN  - 0 (Herbicides)
RN  - 0 (Pesticide Residues)
RN  - 0 (Triazines)
SB  - IM
MH  - Chromatography, Gas
MH  - Herbicides/*analysis
MH  - Pesticide Residues/*analysis
MH  - Solid Phase Extraction
MH  - Triazines/*analysis
MH  - Zea mays/*chemistry
EDAT- 2007/02/10 09:00
MHDA- 2010/06/04 06:00
CRDT- 2007/02/10 09:00
PHST- 2007/02/10 09:00 [pubmed]
PHST- 2010/06/04 06:00 [medline]
PHST- 2007/02/10 09:00 [entrez]
PST - ppublish
SO  - Se Pu. 2006 Nov;24(6):648-51.