PMID- 17361969
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20070724
LR  - 20090804
IS  - 0947-6539 (Print)
IS  - 0947-6539 (Linking)
VI  - 13
IP  - 13
DP  - 2007
TI  - High-density storage of H2 in microporous crystalline silica at ambient 
      conditions.
PG  - 3590-5
AB  - Molecular hydrogen was encapsulated in the cages of clathrasil decadodecasil 3R 
      (DD3R) during the hydrothermal synthesis of this microporous silicate. The 
      crystalline structure of DD3R facilitates high-density hydrogen storage at 
      ambient conditions. Prompt gamma activation analysis (PGAA) revealed that on 
      average about one molecule of H2 is trapped in each (5(12)) cage of DD3R. The 
      presence of molecular hydrogen inside the DD3R framework was confirmed by 
      solid-state 1H NMR spectroscopy. Temperature-programmed decomposition (TPD) in 
      combination with mass spectrometry showed that the encapsulated hydrogen is 
      released upon decomposition of the clathrasil structure. This release can be 
      promoted by the presence of water.
FAU - van den Berg, Annemieke W C
AU  - van den Berg AW
AD  - Ceramic Membrane Centre The Pore, DelftChemTech, Delft University of Technology, 
      Julianalaan 136, 2628 BL Delft, The Netherlands.
FAU - Pescarmona, Paolo P
AU  - Pescarmona PP
FAU - Schoonman, Joop
AU  - Schoonman J
FAU - Jansen, Jacobus C
AU  - Jansen JC
LA  - eng
PT  - Journal Article
PL  - Germany
TA  - Chemistry
JT  - Chemistry (Weinheim an der Bergstrasse, Germany)
JID - 9513783
EDAT- 2007/03/17 09:00
MHDA- 2007/03/17 09:01
CRDT- 2007/03/17 09:00
PHST- 2007/03/17 09:00 [pubmed]
PHST- 2007/03/17 09:01 [medline]
PHST- 2007/03/17 09:00 [entrez]
AID - 10.1002/chem.200601877 [doi]
PST - ppublish
SO  - Chemistry. 2007;13(13):3590-5. doi: 10.1002/chem.200601877.