PMID- 17386531
OWN - NLM
STAT- MEDLINE
DCOM- 20070608
LR  - 20131121
IS  - 1873-4324 (Electronic)
IS  - 0003-2670 (Linking)
VI  - 583
IP  - 1
DP  - 2007 Jan 30
TI  - Speciation of inorganic selenium using capillary electrophoresis-inductively 
      coupled plasma-atomic emission spectrometry with on-line hydride generation.
PG  - 92-7
AB  - A novel and simple hydride generator has been developed. The hydride generator 
      has good stability and high gas liquid separation efficiency. The generator 
      serves as an interface of capillary electrophoresis (CE) and inductively coupled 
      plasma atomic emission spectrometry (ICP-AES). This device eliminates the 
      nebulization step and overcomes the common problem of suction flow resulting from 
      the use of nebulization gas in ICP. Selenium compounds that were separated by CE 
      were converted into the corresponding volatile hydrides, followed by ICP-AES 
      measurement. The effects of the concentration of the hydride generating reagents 
      (HCl and NaBH4), the carrier gas flow rate, and heavy metal interference on Se 
      emission intensity were discussed. The relative standard deviations (RSDs) of 
      peak area, based on six determinations of 50 ng mL(-1) standard of Se(IV) and 
      Se(VI), were 1.5% and 1.8%, respectively. The detection limits (3sigma) of peak 
      area were 2.1 ng mL(-1) and 2.3 ng mL(-1) for Se(IV) and Se(VI), respectively. 
      Speciation analysis of inorganic Se(IV) and Se(IV) species using the 
      HG-CE-ICP-AES system was demonstrated in tap and river water samples.
FAU - Deng, Biyang
AU  - Deng B
AD  - College of Chemistry and Chemical Engineering, Guangxi Normal University, 541004 
      Guilin, China. dengby16@163.com
FAU - Feng, Jinrong
AU  - Feng J
FAU - Meng, Jun
AU  - Meng J
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20060926
PL  - Netherlands
TA  - Anal Chim Acta
JT  - Analytica chimica acta
JID - 0370534
RN  - 0 (Anhydrides)
RN  - 0 (Indicators and Reagents)
RN  - H6241UJ22B (Selenium)
SB  - IM
MH  - Anhydrides/analysis
MH  - Electrophoresis, Capillary/methods
MH  - Indicators and Reagents
MH  - Selenium/*isolation & purification
MH  - Spectrophotometry, Atomic/methods
EDAT- 2007/03/28 09:00
MHDA- 2007/06/09 09:00
CRDT- 2007/03/28 09:00
PHST- 2006/08/05 00:00 [received]
PHST- 2006/09/16 00:00 [revised]
PHST- 2006/09/19 00:00 [accepted]
PHST- 2007/03/28 09:00 [pubmed]
PHST- 2007/06/09 09:00 [medline]
PHST- 2007/03/28 09:00 [entrez]
AID - S0003-2670(06)01961-1 [pii]
AID - 10.1016/j.aca.2006.09.038 [doi]
PST - ppublish
SO  - Anal Chim Acta. 2007 Jan 30;583(1):92-7. doi: 10.1016/j.aca.2006.09.038. Epub 
      2006 Sep 26.