PMID- 17386678
OWN - NLM
STAT- MEDLINE
DCOM- 20070706
LR  - 20131121
IS  - 1873-4324 (Electronic)
IS  - 0003-2670 (Linking)
VI  - 585
IP  - 2
DP  - 2007 Mar 7
TI  - Determination of antimony(III) and total antimony by single-drop microextraction 
      combined with electrothermal atomic absorption spectrometry.
PG  - 300-4
AB  - A simple and sensitive method for using electrothermal atomic absorption 
      spectrometry (ET AAS) with Rh as permanent modifier determination of Sb(III) and 
      total Sb after separation and preconcentration by N-benzoyl-N-phenylhydroxylamine 
      (BPHA)-chloroform single drop has been developed. Parameters, such as pyrolysis 
      and atomization temperature, solvent type, pH, BPHA concentration, extraction 
      time, drop size, stirring rate and sample volume were investigated. Under the 
      optimized experimental conditions, the detection limits (3sigma) were 8.0 ng 
      L(-1) for Sb(III) and 9.2 ng L(-1) for total Sb, respectively. The relative 
      standard deviations (R.S.Ds.) were 6.6% for Sb(III) and 7.1% for total Sb (c=0.2 
      ng mL(-1), n=7), respectively. The enrichment factor was 96. The developed method 
      has been applied successfully to the determination of Sb(III) and total Sb in 
      natural water samples.
FAU - Fan, Zhefeng
AU  - Fan Z
AD  - Department of Chemistry, Shanxi Normal University, Linfen 041004, PR China. 
      zhefengfan@163.com <zhefengfan@163.com>
LA  - eng
PT  - Journal Article
DEP - 20061230
PL  - Netherlands
TA  - Anal Chim Acta
JT  - Analytica chimica acta
JID - 0370534
RN  - 0 (Hydroxylamines)
RN  - 0 (Solvents)
RN  - 059QF0KO0R (Water)
RN  - 304-88-1 (N-benzoyl-N-phenylhydroxylamine)
RN  - 7V31YC746X (Chloroform)
RN  - 9IT35J3UV3 (Antimony)
SB  - IM
MH  - Antimony/*analysis/chemistry
MH  - Chemistry Techniques, Analytical/*methods
MH  - Chloroform/chemistry
MH  - Electrochemistry/*methods
MH  - Hot Temperature
MH  - Hydrogen-Ion Concentration
MH  - Hydroxylamines/chemistry
MH  - Particle Size
MH  - Sensitivity and Specificity
MH  - Solvents/chemistry
MH  - Spectrophotometry, Atomic/*methods
MH  - Temperature
MH  - Time Factors
MH  - Water/chemistry
EDAT- 2007/03/28 09:00
MHDA- 2007/07/07 09:00
CRDT- 2007/03/28 09:00
PHST- 2006/09/11 00:00 [received]
PHST- 2006/12/12 00:00 [revised]
PHST- 2006/12/20 00:00 [accepted]
PHST- 2007/03/28 09:00 [pubmed]
PHST- 2007/07/07 09:00 [medline]
PHST- 2007/03/28 09:00 [entrez]
AID - S0003-2670(06)02459-7 [pii]
AID - 10.1016/j.aca.2006.12.034 [doi]
PST - ppublish
SO  - Anal Chim Acta. 2007 Mar 7;585(2):300-4. doi: 10.1016/j.aca.2006.12.034. Epub 
      2006 Dec 30.