PMID- 17495405
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20070717
LR  - 20190827
IS  - 0910-6340 (Print)
IS  - 0910-6340 (Linking)
VI  - 23
IP  - 5
DP  - 2007 May
TI  - Elimination of matrix effect and simultaneous determination of multi-components 
      in complex systems by matrix coefficient non-linearity multivariate calibration 
      based on single point response signals.
PG  - 581-7
AB  - In order to deal with the matrix effect in the simultaneous determination of 
      multi-components in a complex system, we have developed a novel method named 
      matrix coefficient multivariate calibration method (MCMCM) for simultaneously 
      determining n analytes in complex systems. The calibration models of n analytes, 
      which are based on the experimental data of known samples, are first transformed 
      into n linear equations, and then the equations are solved to obtain matrix 
      calibration coefficients of the analytes in congeneric samples. In this way, the 
      concentrations of n analytes in the unknown sample could be obtained easily and 
      simultaneously by solving another n-variate linear equations with the help of the 
      matrix calibration coefficients obtained-above. The method proposed in this work 
      has been tested by voltammetry and atomic absorption spectrometry (AAS) with 
      satisfactory results. On determining the elements such as Cu, Pb, Cd, Ni, Zn, Fe, 
      Mn, Co, Ca, Mg, etc. in synthetic samples, the relative standard deviations 
      (RSDs) of the results were 0.91 - 4.5%, and the recoveries were 95.8 - 105%. For 
      actual samples, the RSDs and the recoveries were 1.5 - 6.9 and 92.0 - 110%, 
      respectively.
FAU - Zhang, Tai-Ming
AU  - Zhang TM
AD  - College of Chemistry and Chemical Engineering, Central South University, China.
FAU - Yuan, Bin
AU  - Yuan B
FAU - Liang, Yi-Zeng
AU  - Liang YZ
FAU - Cao, Juan
AU  - Cao J
FAU - Pan, Chun-Xiao
AU  - Pan CX
FAU - Ying, Bin
AU  - Ying B
FAU - Lu, Di-Yi
AU  - Lu DY
LA  - eng
PT  - Journal Article
PL  - Switzerland
TA  - Anal Sci
JT  - Analytical sciences : the international journal of the Japan Society for 
      Analytical Chemistry
JID - 8511078
EDAT- 2007/05/15 09:00
MHDA- 2007/05/15 09:01
CRDT- 2007/05/15 09:00
PHST- 2007/05/15 09:00 [pubmed]
PHST- 2007/05/15 09:01 [medline]
PHST- 2007/05/15 09:00 [entrez]
AID - JST.JSTAGE/analsci/23.581 [pii]
AID - 10.2116/analsci.23.581 [doi]
PST - ppublish
SO  - Anal Sci. 2007 May;23(5):581-7. doi: 10.2116/analsci.23.581.