PMID- 17580692
OWN - NLM
STAT- MEDLINE
DCOM- 20100615
LR  - 20161018
IS  - 1000-8713 (Print)
IS  - 1000-8713 (Linking)
VI  - 25
IP  - 2
DP  - 2007 Mar
TI  - [Simultaneous determination of captan and folpet pesticide residues in apples by 
      solid-phase extraction and high performance liquid chromatography].
PG  - 226-9
AB  - A method for the simultaneous determination of captan and folpet pesticide 
      residues in apples was developed by solid-phase extraction and high performance 
      liquid chromatography. The sample was extracted with acetonitrile and cleaned-up 
      by a mixture of homemade sorbent and silica gel with 
      hexane-dichloromethane-acetonitrile (50:49: 1, v/v) as the eluent. The cleaned 
      effects by using Florisil column, amino column, the mixed sorbent were compared, 
      and the effect of the mixed sorbent was the best. The optimal analytical 
      conditions were follow as: an methanol-acetonitrile-water (50: 5:45, v/v) 
      containing 0. 1 mmol/L acetic-acetate buffer (pH 3. 80) as the mobile phase, 
      detection at 210 nm. The method had a good linear relationship in the range of 0. 
      40 - 8. 00 mg/kg for captan and folpet (r > 0. 999 9). The detection limits of 
      captan and folpet were 0. 27 mg/kg and 0. 20 mg/kg, respectively. The relative 
      standard deviations (RSDs) of retention time were no more than 0. 60%. The 
      average recoveries of captan and folpet from the apples spiked at three levels 
      ranged from 69. 3% - 106% and 101% - 108%, with RSD of 3. 7% - 4. 7% and 1. 3% - 
      5. 4%, respectively.
FAU - Wang, Shuju
AU  - Wang S
AD  - Ocean University of China, Qingdao 266003, China.
FAU - Yu, Yanbin
AU  - Yu Y
FAU - Tan, Peigong
AU  - Tan P
FAU - Miao, Zaijing
AU  - Miao Z
FAU - Wei, Yishan
AU  - Wei Y
LA  - chi
PT  - English Abstract
PT  - Journal Article
PL  - China
TA  - Se Pu
JT  - Se pu = Chinese journal of chromatography
JID - 9424804
RN  - 0 (Pesticide Residues)
RN  - 0 (Phthalimides)
RN  - EOL5G26Q9F (Captan)
RN  - X5NFK36917 (folpet)
SB  - IM
MH  - Captan/*analysis
MH  - Chromatography, High Pressure Liquid/*methods
MH  - Hydrogen-Ion Concentration
MH  - Malus/*chemistry
MH  - Pesticide Residues/*analysis
MH  - Phthalimides/*analysis
MH  - Reproducibility of Results
MH  - Solid Phase Extraction/*methods
EDAT- 2007/06/22 09:00
MHDA- 2010/06/16 06:00
CRDT- 2007/06/22 09:00
PHST- 2007/06/22 09:00 [pubmed]
PHST- 2010/06/16 06:00 [medline]
PHST- 2007/06/22 09:00 [entrez]
PST - ppublish
SO  - Se Pu. 2007 Mar;25(2):226-9.