PMID- 17681427 OWN - NLM STAT- MEDLINE DCOM- 20080506 LR - 20071105 IS - 0304-3894 (Print) IS - 0304-3894 (Linking) VI - 149 IP - 3 DP - 2007 Nov 19 TI - Chemical recycling of plastic wastes made from polyethylene (LDPE and HDPE) and polypropylene (PP). PG - 536-42 AB - The recycling of either model polymers or waste products based on low-density polyethylene (LDPE), high-density polyethylene (HDPE) or polypropylene (PP) is examined using the dissolution/reprecipitation method, as well as pyrolysis. In the first technique, different solvents/non-solvents were examined at different weight percent amounts and temperatures using as raw material both model polymers and commercial products (packaging film, bags, pipes, food-retail outlets). The recovery of polymer in every case was greater than 90%. FT-IR spectra and tensile mechanical properties of the samples before and after recycling were measured. Furthermore, catalytic pyrolysis was carried out in a laboratory fixed bed reactor with an FCC catalyst using again model polymers and waste products as raw materials. Analysis of the derived gases and oils showed that pyrolysis gave a mainly aliphatic composition consisting of a series of hydrocarbons (alkanes and alkenes), with a great potential to be recycled back into the petrochemical industry as a feedstock for the production of new plastics or refined fuels. FAU - Achilias, D S AU - Achilias DS AD - Laboratory of Organic Chemical Technology, Department of Chemistry, Aristotle University of Thessaloniki, 541 24 Thessaloniki, Greece. axilias@chem.auth.gr FAU - Roupakias, C AU - Roupakias C FAU - Megalokonomos, P AU - Megalokonomos P FAU - Lappas, A A AU - Lappas AA FAU - Antonakou, Epsilon V AU - Antonakou EV LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20070629 PL - Netherlands TA - J Hazard Mater JT - Journal of hazardous materials JID - 9422688 RN - 0 (Hydrocarbons) RN - 0 (Polyethylenes) RN - 0 (Polymers) RN - 0 (Waste Products) SB - IM MH - Catalysis MH - Chemistry/methods MH - Conservation of Natural Resources/*methods MH - Equipment Design MH - Food Packaging MH - Hydrocarbons/chemistry MH - Polyethylenes/*chemistry MH - Polymers/chemistry MH - *Refuse Disposal MH - Spectroscopy, Fourier Transform Infrared MH - Tensile Strength MH - Waste Products EDAT- 2007/08/08 09:00 MHDA- 2008/05/07 09:00 CRDT- 2007/08/08 09:00 PHST- 2007/08/08 09:00 [pubmed] PHST- 2008/05/07 09:00 [medline] PHST- 2007/08/08 09:00 [entrez] AID - S0304-3894(07)00947-8 [pii] AID - 10.1016/j.jhazmat.2007.06.076 [doi] PST - ppublish SO - J Hazard Mater. 2007 Nov 19;149(3):536-42. doi: 10.1016/j.jhazmat.2007.06.076. Epub 2007 Jun 29.