PMID- 17920882 OWN - NLM STAT- MEDLINE DCOM- 20080616 LR - 20231213 IS - 0960-8524 (Print) IS - 0960-8524 (Linking) VI - 99 IP - 10 DP - 2008 Jul TI - Kinetics and thermodynamics of basic dye sorption on phosphoric acid esterifying soybean hull with solid phase preparation technique. PG - 4510-4 AB - In this paper, the solid phase preparation method of a cationic sorbent, which bears hydroxyl groups of phosphoric acid derived from esterified soybean hull (ESH), was reported. The sorption kinetics and thermodynamics of two basic dyes, acridine orange (AO) and malachite green (MG), from aqueous solution onto ESH were investigated with a batch system. The isothermal data of dye sorptions followed the Langmuir model better than the Freundlich model. The maximum sorption capacity (Q(m)) of ESH for AO and MG was 238.1 mg/g and 178.57 mg/g, respectively. The dye sorption processes could be described by the pseudo-second-order kinetic model. The thermodynamic study indicated that the dye sorptions were spontaneous and exothermic. Lower temperatures were favorable for the sorption processes. FAU - Gong, Renmin AU - Gong R AD - The Laboratory of Bio-Macromolecular Evolution, College of Life Science, Anhui Normal University, Wuhu 241000, PR China. FAU - Sun, Jin AU - Sun J FAU - Zhang, Demin AU - Zhang D FAU - Zhong, Keding AU - Zhong K FAU - Zhu, Guoping AU - Zhu G LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20071024 PL - England TA - Bioresour Technol JT - Bioresource technology JID - 9889523 RN - 0 (Cations) RN - 0 (Coloring Agents) RN - 0 (Indicators and Reagents) RN - 0 (Industrial Waste) RN - 0 (Phosphoric Acids) RN - 0 (Rosaniline Dyes) RN - 0 (Water Pollutants, Chemical) RN - 12058M7ORO (malachite green) RN - 27YLU75U4W (Phosphorus) RN - E4GA8884NN (phosphoric acid) RN - F30N4O6XVV (Acridine Orange) SB - IM MH - Acridine Orange/chemistry MH - Adsorption MH - Biotechnology/*methods MH - Cations MH - Coloring Agents/*chemistry/pharmacology MH - Indicators and Reagents/*chemistry/pharmacology MH - Industrial Waste MH - Kinetics MH - Models, Chemical MH - Phosphoric Acids/*chemistry MH - Phosphorus/chemistry MH - Rosaniline Dyes/chemistry MH - Glycine max MH - Thermodynamics MH - Water Pollutants, Chemical EDAT- 2007/10/09 09:00 MHDA- 2008/06/17 09:00 CRDT- 2007/10/09 09:00 PHST- 2007/04/21 00:00 [received] PHST- 2007/08/27 00:00 [revised] PHST- 2007/08/29 00:00 [accepted] PHST- 2007/10/09 09:00 [pubmed] PHST- 2008/06/17 09:00 [medline] PHST- 2007/10/09 09:00 [entrez] AID - S0960-8524(07)00723-7 [pii] AID - 10.1016/j.biortech.2007.08.061 [doi] PST - ppublish SO - Bioresour Technol. 2008 Jul;99(10):4510-4. doi: 10.1016/j.biortech.2007.08.061. Epub 2007 Oct 24.