PMID- 17970103
OWN - NLM
STAT- MEDLINE
DCOM- 20100610
LR  - 20231213
IS  - 1000-8713 (Print)
IS  - 1000-8713 (Linking)
VI  - 25
IP  - 4
DP  - 2007 Jul
TI  - [Determination of glyphosate and aminomethylphosphonic acid residues in foods 
      using high performance liquid chromatography-mass spectrometry/mass 
      spectrometry].
PG  - 486-90
AB  - A method for the determination of glyphosate (PMG) and aminomethylphosphonic acid 
      (AMPA) residues in plant products, such as rice, wheat, vegetables, fruits and 
      tea, pig and chicken muscles, aquatic products, chestnut, honey, etc., was 
      developed using high performance liquid chromatography coupled to tandem mass 
      spectrometry (HPLC-MS/MS). In this method, PMG and AMPA were extracted with water 
      from samples, defatted using an extraction step with dichloromethane, and 
      purified using a cation-exchange (CAX) solid phase extraction cartridge. Then, 
      these were derived using fluorenylmethylchloroformate (FMOC-Cl) in borate buffer 
      for subsequent HPLC-MS/MS analysis. Isotope-labeled PMG 1, 2(13)- C(15) N was 
      used as the internal standard for the quantitative analysis of two residues. For 
      all samples, the recoveries ranged from 80.0% to 104% and the relative standard 
      deviations (RSDs) ranged from 6.7% to 18.2%. The limit of quantification (LOQ) 
      was determined to be 0.05 mg/kg with a linear range of 0.20-10 microg/L. It is 
      demonstrated that this method is reliable and sensitive for the analysis of PMG 
      and APMA with low concentrations in foods.
FAU - Li, Bo
AU  - Li B
AD  - Shanghai Entry-Exit Inspection and Quarantine Bureau, Shanghai 200135, China. 
      lib@shciq.gov.cn
FAU - Deng, Xiaojun
AU  - Deng X
FAU - Guo, Dehua
AU  - Guo D
FAU - Jin, Shuping
AU  - Jin S
LA  - chi
PT  - Journal Article
PL  - China
TA  - Se Pu
JT  - Se pu = Chinese journal of chromatography
JID - 9424804
RN  - 0 (Isoxazoles)
RN  - 0 (Organophosphonates)
RN  - 0 (Tetrazoles)
RN  - J090588E6X 
      (2-amino-3-(3-hydrox-5(2-methyl-2H-tetrazol-5-yl)isoxazol-4-yl)propionic acid)
RN  - TE7660XO1C (Glycine)
SB  - IM
MH  - Chromatography, High Pressure Liquid/*methods
MH  - *Food Microbiology
MH  - Glycine/*analogs & derivatives/analysis
MH  - Isoxazoles
MH  - Organophosphonates/*analysis
MH  - Tandem Mass Spectrometry/*methods
MH  - Tetrazoles
MH  - Glyphosate
EDAT- 2007/11/01 09:00
MHDA- 2010/06/11 06:00
CRDT- 2007/11/01 09:00
PHST- 2007/11/01 09:00 [pubmed]
PHST- 2010/06/11 06:00 [medline]
PHST- 2007/11/01 09:00 [entrez]
PST - ppublish
SO  - Se Pu. 2007 Jul;25(4):486-90.