PMID- 17990546
OWN - NLM
STAT- MEDLINE
DCOM- 20081010
LR  - 20161018
IS  - 0250-3301 (Print)
IS  - 0250-3301 (Linking)
VI  - 28
IP  - 9
DP  - 2007 Sep
TI  - [Treatment of 4, 4'-dBB in aqueous solution using O3/H2O2 system and its 
      synergetic kinetics].
PG  - 1998-2003
AB  - A comparative study of O3 alone and O3/H2O2 was made to evaluate their respective 
      effectiveness for removal of persistent organic pollutants (POPs) from water with 
      4, 4'-dibro minated biphenyl (4, 4'-DBB) as the model pollutant, and UV254 was 
      used as the surrogate parameter for TOC and DOC. It was found that both processes 
      enhanced the removal rate. Especially, it has been made a further enhancement of 
      the removal of 4, 4'-DBB as H2O2 was added under the alkaline-condition. The 
      final removal rate of 4 mg/L 4, 4'-DBB solution reached 78.0% after reacting for 
      270 min, while the UV254 value varies with the removal rate and reached 
      76.9%-77.8% ultimately. It means that the total organic carbon has been removed 
      obviously. Two kinds of solution of different concentration with the same amount 
      of oxidant reacting for the same time have been compared with each other and the 
      results showed that the higher the initial concentration was, the smaller the 
      removal rate was, however, the more the absolute amount could be removed. It was 
      also found that 4, 4'-DBB's removal followed pseudo-first order reaction and the 
      promoted factor f for 4, 4'-DBB removal rate constant was about 1.54.
FAU - Wang, Lei
AU  - Wang L
AD  - Institute of Sonochemical Engineering, Nanjing University of Technology, Nanjing 
      210009, China.
FAU - Chen, Jin-feng
AU  - Chen JF
FAU - Lu, Xiao-ping
AU  - Lu XP
FAU - Han, Ping-fang
AU  - Han PF
LA  - chi
PT  - Comparative Study
PT  - English Abstract
PT  - Journal Article
PL  - China
TA  - Huan Jing Ke Xue
JT  - Huan jing ke xue= Huanjing kexue
JID - 8405344
RN  - 0 (4,4'-di-tert-butylbiphenyl)
RN  - 0 (Biphenyl Compounds)
RN  - 0 (Water Pollutants, Chemical)
RN  - 66H7ZZK23N (Ozone)
RN  - BBX060AN9V (Hydrogen Peroxide)
SB  - IM
MH  - Biphenyl Compounds/*chemistry
MH  - Hydrogen Peroxide/*chemistry
MH  - Kinetics
MH  - Oxidation-Reduction
MH  - Ozone/*chemistry
MH  - Water Pollutants, Chemical/*chemistry
MH  - Water Purification/*methods
EDAT- 2007/11/10 09:00
MHDA- 2008/10/11 09:00
CRDT- 2007/11/10 09:00
PHST- 2007/11/10 09:00 [pubmed]
PHST- 2008/10/11 09:00 [medline]
PHST- 2007/11/10 09:00 [entrez]
PST - ppublish
SO  - Huan Jing Ke Xue. 2007 Sep;28(9):1998-2003.