PMID- 17996921 OWN - NLM STAT- MEDLINE DCOM- 20080603 LR - 20181201 IS - 0043-1354 (Print) IS - 0043-1354 (Linking) VI - 42 IP - 4-5 DP - 2008 Feb TI - A new mathematical model to evaluate simazine removal in three different immobilized-biomass reactors. PG - 1035-42 AB - A new mathematical model based on the cinetical Langmuir equation is developed to interpret and predict the effectiveness of simazine (SZ) removal in immobilized-biomass reactor (IBR), to consider herbicide-support affinity (Cx), and herbicide-cell affinity (Cy). Three solid supports: sepiolite monolith, granular sepiolite, and alginate were used in pilot-scale reactors that were inoculated with Klebsiella planticola DSZ. The abiotic process was analysed by measuring the SZ sorption capacity of the reactor supports. Sepiolite monolith showed the maximum value for herbicide-support affinity (28.02+/-0.9%). The effectiveness of the biotic process was estimated considering the formation of biomass and SZ biodegradation. Granular sepiolite showed either higher affinity with SZ and viability rate (0.90) throughout the process, and SZ removal rate was 3.39+/-0.06 mg/h. The mathematical model presented in this paper provides useful insights into the interpretation of experimental data as well as prediction for the implementation of biological reactors. FAU - Martin, M AU - Martin M AD - Departamento de Bioquimica y Biologia Molecular IV, Facultad de Veterinaria, Universidad Complutense de Madrid, Avda. Puerta de Hierro s/n, 28040 Madrid, Spain. margamar@vet.ucm.es FAU - Casasus, L AU - Casasus L FAU - Garbi, C AU - Garbi C FAU - Nande, M AU - Nande M FAU - Vargas, R AU - Vargas R FAU - Robla, J I AU - Robla JI FAU - Sanchez, M AU - Sanchez M FAU - Allende, J L AU - Allende JL LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't DEP - 20071004 PL - England TA - Water Res JT - Water research JID - 0105072 RN - 0 (Alginates) RN - 0 (Herbicides) RN - 0 (Hexuronic Acids) RN - 0 (Magnesium Silicates) RN - 8A5D83Q4RW (Glucuronic Acid) RN - C2E1CI501T (magnesium trisilicate) RN - SG0C34SMY3 (Simazine) SB - IM MH - Adsorption MH - Alginates/chemistry MH - Biodegradation, Environmental MH - Biomass MH - *Bioreactors MH - Glucuronic Acid/chemistry MH - *Herbicides/chemistry/metabolism MH - Hexuronic Acids/chemistry MH - *Klebsiella/chemistry/metabolism/ultrastructure MH - Magnesium Silicates/chemistry MH - Microscopy, Electron, Scanning MH - *Models, Biological MH - *Simazine/chemistry/metabolism EDAT- 2007/11/13 09:00 MHDA- 2008/06/05 09:00 CRDT- 2007/11/13 09:00 PHST- 2006/12/21 00:00 [received] PHST- 2007/07/18 00:00 [revised] PHST- 2007/09/26 00:00 [accepted] PHST- 2007/11/13 09:00 [pubmed] PHST- 2008/06/05 09:00 [medline] PHST- 2007/11/13 09:00 [entrez] AID - S0043-1354(07)00629-X [pii] AID - 10.1016/j.watres.2007.09.026 [doi] PST - ppublish SO - Water Res. 2008 Feb;42(4-5):1035-42. doi: 10.1016/j.watres.2007.09.026. Epub 2007 Oct 4.