PMID- 18161307
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20100617
LR  - 20161018
IS  - 1000-8713 (Print)
IS  - 1000-8713 (Linking)
VI  - 25
IP  - 5
DP  - 2007 Sep
TI  - [Preparation of poly (trifluoropropyl) methylsiloxane coating for solid-phase 
      microextraction and its application for the analysis of phenolic compounds in sea 
      water].
PG  - 614-8
AB  - The poly (trifluoropropyl) methylsiloxane (PTFPMS) coating was prepared as 
      solid-phase microextraction (SPME) coating by sol-gel technique. The coating has 
      a porous microstructure and the thickness was 10 microm. Since the PTFPMS phase 
      contains the functional group of -C2H4CF3, it exhibits high affinity to compounds 
      containing electron-attracting groups. The PTFPMS phase can withstand desorption 
      temperature up to 280 degrees C. The lifetime of the fiber SPME is more than 150 
      times. This coating was used to analyse the phenolic compounds in water samples 
      by head-space solid-phase microextraction (HS-SPME) method. The parameters 
      affecting the extraction efficiency, such as extraction mode, extraction 
      temperature, extraction time, ion strength and pH, were optimized. The limits of 
      detection (LODs) of the method were 0.02 - 1.2 microg/L. The relative standard 
      deviations (RSDs) of single fiber and fiber-to-fiber (n = 5 ) were less than 
      4.4%, and 15.7%, respectively. The results indicated that the sol-gel method has 
      good repeatability for the preparation of the PTFPMS coating.
FAU - Guan, Wenna
AU  - Guan W
AD  - Department of Instrumentation and Analytical Chemistry, Dalian Institute of 
      Chemical Physics, the Chinese Academy of Sciences, Dalian 116023, China. 
      wenaguan@yahoo.com.cn
FAU - Xu, Feng
AU  - Xu F
FAU - Lian, Mei
AU  - Lian M
FAU - Xu, Yuan
AU  - Xu Y
FAU - Guan, Yafeng
AU  - Guan Y
LA  - chi
PT  - English Abstract
PT  - Journal Article
PL  - China
TA  - Se Pu
JT  - Se pu = Chinese journal of chromatography
JID - 9424804
EDAT- 2007/12/29 09:00
MHDA- 2007/12/29 09:01
CRDT- 2007/12/29 09:00
PHST- 2007/12/29 09:00 [pubmed]
PHST- 2007/12/29 09:01 [medline]
PHST- 2007/12/29 09:00 [entrez]
PST - ppublish
SO  - Se Pu. 2007 Sep;25(5):614-8.