PMID- 18198022
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20080131
LR  - 20080116
IS  - 0003-7028 (Print)
IS  - 0003-7028 (Linking)
VI  - 61
IP  - 12
DP  - 2007 Dec
TI  - Experimental vibrational study of imidazolium-based ionic liquids: Raman and 
      infrared spectra of 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide 
      and 1-ethyl-3-methylimidazolium ethylsulfate.
PG  - 1306-11
LID - 10.1366/000370207783292000 [doi]
AB  - The vibrational structure of two room-temperature ionic liquids with the cation 
      1-ethyl-3-methylimidazolium [EMIM] and the respective anions 
      bis(trifluoromethylsulfonyl)imide [TFSI] and ethylsulfate [EtOSO(3)] is 
      investigated. In particular, attenuated total reflection (ATR) infrared (IR) as 
      well as Raman spectra in the spectral range from 500 to 3500 cm(-1) have been 
      recorded and analyzed. Moreover, the depolarization ratios of the Raman lines are 
      determined. The individual peaks are assigned to the corresponding vibrational 
      modes of the molecules. While the CH stretching region around 3000 cm(-1) is 
      dominating in Raman spectra, it is remarkably weak in IR spectra. Finally, the 
      results for 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide are 
      compared to previous studies of single ions available in the literature. This 
      comparison shows good agreement.
FAU - Kiefer, Johannes
AU  - Kiefer J
AD  - Lehrstuhl fur Technische Thermodynamik, Universitat Erlangen-Nurnberg, D-91058 
      Erlangen, Germany. jk@ltt.uni-erlangen.de
FAU - Fries, Juergen
AU  - Fries J
FAU - Leipertz, Alfred
AU  - Leipertz A
LA  - eng
PT  - Journal Article
PL  - United States
TA  - Appl Spectrosc
JT  - Applied spectroscopy
JID - 0372406
EDAT- 2008/01/17 09:00
MHDA- 2008/01/17 09:01
CRDT- 2008/01/17 09:00
PHST- 2008/01/17 09:00 [pubmed]
PHST- 2008/01/17 09:01 [medline]
PHST- 2008/01/17 09:00 [entrez]
AID - 10.1366/000370207783292000 [doi]
PST - ppublish
SO  - Appl Spectrosc. 2007 Dec;61(12):1306-11. doi: 10.1366/000370207783292000.