PMID- 18200859 OWN - NLM STAT- MEDLINE DCOM- 20080312 LR - 20190715 IS - 0013-936X (Print) IS - 0013-936X (Linking) VI - 41 IP - 24 DP - 2007 Dec 15 TI - Perfluorinated acids in air, rain, snow, surface runoff, and lakes: relative importance of pathways to contamination of urban lakes. PG - 8328-34 AB - Concentrations of perfluorinated acids (PFAs) were measured in various environmental matrices (air, rain, snow, surface runoff water, and lake water) in an urban area, to enable identification of sources and pathways of PFAs to urban water bodies. Total PFA concentrations ranged from 8.28 to 16.0 pg/ m3 (mean 11.3) in bulk air (sum of vapor and particulate phases), 0.91 to 13.2 ng/L (6.19) in rainwater, 0.91 to 23.9 ng/L (7.98) in snow, 1.11-81.8 ng/L (15.1 ng/L) in surface runoff water (SRW), and 9.49 to 35.9 ng/L (21.8) in lake water. Perfluorooctanoic acid (PFOA) was the predominant compound, accounting for > 35% of the total PFA concentrations, in all environmental matrices analyzed. Concentrations and relative compositions of PFAs in SRW were similar to those found for urban lakes. SRW contributes to contamination by PFOA in urban lakes. The measured concentration ratios of FTOH to PFOA in air were 1-2 orders of magnitude lower than the ratios calculated based on an assumption of exclusive atmospheric oxidation of FTOHs. Nevertheless, the mass balance analysis suggested the presence of an unknown input pathway that could contribute to a significant amount of total PFOA loadings to the lake. Flux estimates of PFOA at the air-water interface in the urban lake suggest net volatilization from water. FAU - Kim, Seung-Kyu AU - Kim SK AD - Institute of Environmental Protection and Safety, NeoEnBiz Co., Rm 904, Byuksan Digital Valley II, Gasandong 481-10, Geumcheon gu, Seoul 153-783, South Korea. FAU - Kannan, Kurunthachalam AU - Kannan K LA - eng PT - Journal Article PT - Research Support, Non-U.S. Gov't PL - United States TA - Environ Sci Technol JT - Environmental science & technology JID - 0213155 RN - 0 (Air Pollutants) RN - 0 (Fluorine Compounds) RN - 0 (Water Pollutants, Chemical) SB - IM MH - Air Pollutants/*analysis MH - Fluorine Compounds/*analysis MH - Fresh Water MH - Rain/*chemistry MH - Sensitivity and Specificity MH - Snow/*chemistry MH - Water Pollutants, Chemical/*analysis EDAT- 2008/01/19 09:00 MHDA- 2008/03/13 09:00 CRDT- 2008/01/19 09:00 PHST- 2008/01/19 09:00 [pubmed] PHST- 2008/03/13 09:00 [medline] PHST- 2008/01/19 09:00 [entrez] AID - 10.1021/es072107t [doi] PST - ppublish SO - Environ Sci Technol. 2007 Dec 15;41(24):8328-34. doi: 10.1021/es072107t.