PMID- 18348043
OWN - NLM
STAT- MEDLINE
DCOM- 20081110
LR  - 20191210
IS  - 1944-0057 (Electronic)
IS  - 1944-0057 (Linking)
VI  - 25
IP  - 4
DP  - 2008 Apr
TI  - Pesticide residues in grapes from vineyards included in integrated pest 
      management in Slovenia.
PG  - 438-43
LID - 10.1080/02652030701558490 [doi]
AB  - Although the list of pesticides used in integrated pest management (IPM) in grape 
      growing and their annual application rates are limited, we are still confronted 
      with the problem of pesticide residues in grapes. This paper presents the results 
      of pesticide monitoring of 47 samples of wine grapes (Vitis vinifera L.) from the 
      2006 vintage from vineyards included in IPM. The grape samples were analysed for 
      the presence of 67 pesticides. Among them 20 were allowed in IPM in 2006. Grapes 
      were sampled at harvest. Two internal analytical methods were used for the 
      determination of pesticides: gas chromatography-mass spectrometry (GC-MS) method 
      for the determination of dithiocarbamates and a multi-residue GC-MS method. One 
      grape sample (2.1%) contained no residues or they were below the limit of 
      detection, 28 samples (59.6%) contained residues lower or equal than maximum 
      residue levels (MRLs), and 18 samples (38.3%) exceeded national MRLs for 
      cyprodinil (the concentration range was 0.03-0.40 mg kg(-1) of cyprodinil) and 
      fludioxonil (concentration was 0.03 mg kg(-1) of fludioxonil). Multiple residues 
      were found in 41 samples (87.2%). The highest number of pesticides detected per 
      sample was seven. No violation of pesticides allowed in IPM was observed. Folpet 
      (97.9%), cyprodinil (51.1%), dithiocarbamates (44.7%), chlorothalonil (23.4%), 
      chlorpyriphos (19.1%) and pyrimethanil (14.9%) were the most frequently found 
      pesticides in grapes. Risk assessment showed that the exceeded concentrations of 
      cyprodinil and fludioxonil did not represent any risk for consumer's health (the 
      national estimate of short-term intake as a percentage of the acceptable daily 
      intake was below 100%).
FAU - Cesnik, H Basa
AU  - Cesnik HB
AD  - Agricultural Institute of Slovenia, Central Laboratories, Ljubljana, SI-1000 
      Slovenia. helena.basa@kis.si
FAU - Gregorcic, A
AU  - Gregorcic A
FAU - Cus, F
AU  - Cus F
LA  - eng
PT  - Journal Article
PT  - Multicenter Study
PT  - Validation Study
PL  - England
TA  - Food Addit Contam Part A Chem Anal Control Expo Risk Assess
JT  - Food additives & contaminants. Part A, Chemistry, analysis, control, exposure & 
      risk assessment
JID - 101485040
RN  - 0 (Dioxoles)
RN  - 0 (Fungicides, Industrial)
RN  - 0 (Pesticide Residues)
RN  - 0 (Pyrimidines)
RN  - 0 (Pyrroles)
RN  - 42P6T6OFWZ (cyprodinil)
RN  - ENS9J0YM16 (fludioxonil)
SB  - IM
MH  - Dioxoles/analysis
MH  - Fungicides, Industrial/*analysis
MH  - Gas Chromatography-Mass Spectrometry
MH  - Humans
MH  - Maximum Allowable Concentration
MH  - Pesticide Residues/*analysis
MH  - Pyrimidines/analysis
MH  - Pyrroles/analysis
MH  - Slovenia
MH  - Vitis/*chemistry
EDAT- 2008/03/19 09:00
MHDA- 2008/11/11 09:00
CRDT- 2008/03/19 09:00
PHST- 2008/03/19 09:00 [pubmed]
PHST- 2008/11/11 09:00 [medline]
PHST- 2008/03/19 09:00 [entrez]
AID - 790414839 [pii]
AID - 10.1080/02652030701558490 [doi]
PST - ppublish
SO  - Food Addit Contam Part A Chem Anal Control Expo Risk Assess. 2008 
      Apr;25(4):438-43. doi: 10.1080/02652030701558490.